| Автор | DIXON, W. T. |
| Автор | NORMAN, R. O. C. |
| Дата выпуска | 1962 |
| dc.description | THE reduction of hydrogen peroxide by transition metal ions is thought to involve hydroxyl radicals as intermediates<sup>1</sup>. We have found that dilute solutions of titanous ion and hydrogen peroxide (about 10<sup>â 2</sup> M) react together to form a free radical of short life. This has been observed by using a flow system in which the reactants are mixed just before entering the cavity of a Varian electron spin resonance spectrometer. The spectrum is a single line near g = 2, width about 3 gauss, the intensity of which at maximum flow-rate is proportional to [Ti<sup>3+</sup>] and [H2O2] when these are low. |
| Формат | application.pdf |
| Название | Free Radicals formed during the Oxidation and Reduction of Peroxides |
| Тип | LETTERS TO NATURE |
| DOI | 10.1038/196891a0 |
| Print ISSN | 0028-0836 |
| Журнал | Nature |
| Том | 196 |
| Первая страница | 891 |
| Последняя страница | 892 |
| Выпуск | 4857 |
