Автор |
Carr, Christopher, M. |
Автор |
Leaver, Ian, H. |
Автор |
Hughes, Anthony, E. |
Дата выпуска |
1986 |
dc.description |
The surface analysis technique of x-ray photoelectron spectroscopy (XPS) has been used to investigate the chemical composition and reactivity of the wool epicuticle. Approximate relative proportions of protein and lipid material in the epicuticle have been deduced from the surface elemental ratios; the sulfur content of the proteins in the epicuticle was estimated to be about 9% by weight. Treating wool with potassium t-butoxide in anhydrous t-butanol, a reagent that is reported to cause specific epicuticle modification, caused only minor changes in the elemental composition of the fiber surface. There were marked changes, however, in the sulfur (2p) photoelectron spec trum. Approximately one third of the cystine residues in the epicuticle were converted to cysteic acid residues. Evidence was also obtained for the partial conversion of cystine residues into lanthionine residues. |
Издатель |
Sage Publications |
Название |
X-Ray Photoelectron Spectroscopic Study of the Wool Fiber Surface |
Тип |
Journal Article |
DOI |
10.1177/004051758605600710 |
Print ISSN |
0040-5175 |
Журнал |
Textile Research Journal |
Том |
56 |
Первая страница |
457 |
Последняя страница |
461 |
Аффилиация |
Carr, Christopher, M., CSIRO Division of Protein Chemistry, Parkville 3052, Australia |
Аффилиация |
Leaver, Ian, H., CSIRO Division of Protein Chemistry, Parkville 3052, Australia |
Аффилиация |
Hughes, Anthony, E., CSIRO Division of Materials Science, Parkville 3052, Australia |
Выпуск |
7 |
Библиографическая ссылка |
Bradbury, J.H. , The Structure and Chemistry of Keratin Fibres, Adv. Protein Chem. 27, 111-211 (1973). |
Библиографическая ссылка |
Bradbury, J.H. , and King, N.L.R., The Chemical Composition of Wool, The Epicuticle, Aust. J. Biol. Sci. 21, 375-384 (1968). |
Библиографическая ссылка |
Carr, C.M., Photoelectron and Fluorescence Spectroscopic Studies of the Nature of Wool-Polymer Systems, Doctoral thesis, University College , Cardiff, 1983. |
Библиографическая ссылка |
Crewther, W.G., Primary Structure and Chemical Properties of Wool, in "Proc. 5th Int. Wool Text. Res. Conf.," vol. I, Aachen, 1975, pp. 1-101. |
Библиографическая ссылка |
Cuthbertson, W.R., and Phillips , H., TheAction of Alkalis on Wool, Biochem. J.39, 7-23 (1945). |
Библиографическая ссылка |
Danehy, J.P. , and Hunter, W.E., The Alkaline Decomposition of Organic Disulfides, J. Org. Chem. 32, 2047-2053 (1967). |
Библиографическая ссылка |
Dobb, M.G., Murray, R., and Sikorski, J., Specific Labelling of Thiol Groups in Mammalian Keratin suitable for Electron Microscope Studies, J. Microsc. Oxford96, 285-299 (1972). |
Библиографическая ссылка |
Gillespie, J.M., and Marshall, R.C., Variability in the Proteins of Wool and Hair, in "Proc. 6th Int. Wool. Text. Res. Conf.," vol. II, Pretoria , 1980, pp. 67-77. |
Библиографическая ссылка |
Harrap, B.S. , and Gillespie, J.M., Further Study of the Extraction of Reduced Proteins from Wool, Aust. J. Biol. Sci. 16, 542-556 (1963). |
Библиографическая ссылка |
Inglis, A.S. , McMahon, D.T.W., Roxburgh, C.M., and Takayanagi , H., Single Analysis for Cysteine, Cystine and Tryptophan in Proteins, Anal. Biochem. 72, 86-94 (1976). |
Библиографическая ссылка |
Leeder, J.D. , and Rippon, J.A., Changes Induced in the Properties of Wool by Specific Epicuticle Modification, J. Soc. Dyers Colour . 101, 11-16 (1985). |
Библиографическая ссылка |
Leeder, J.D. , and Marshall, R.C., Readily-Extracted Proteins from Merino Wool, Textile Res. J. 52, 245-249 (1982). |
Библиографическая ссылка |
Lindberg, B.J. , Hamrin, K., Johansson, G., Gelius, U., Fahlman, A., Nordling, C., and Siegbahn, K., Molecular Spectroscopy by Means of ESCA, Physica Scripta 1, 286-298 ( 1970). |
Библиографическая ссылка |
Lundt, B.F. , Johansen, N.L., Volund, A., and Markussen, J., Removal of t-Butyl and t-Butoxycarbonyl Protecting Groups with Trifluoroacetic Acid, Int. J. Pept. Protein Res. 12, 258-268 (1978). |
Библиографическая ссылка |
Maclaren, J.A., and Milligan, B., "Wool Science, The Chemical Reactivity of the Wool Fibre," Science Press, Marrickville, NSW, Australia, 1981. |
Библиографическая ссылка |
Makinson, K.R., "Shrinkproofing of Wool," Marcel Dekker, New York, 1979, pp. 10-16. |
Библиографическая ссылка |
Millard, M.M., Surface Characterization of Biological Materials by X-Ray Photoelectron Spectroscopy, in "Contemporary Topics in Analytical and Clinical Chemistry," D. M. Hercules, G. M. Hieftje , L. R. Snyder, and M. A. Evenson, Eds., Plenum Press, New York, 1978, pp. 1-55. |
Библиографическая ссылка |
Millard, M.M. , Surface Analysis of Plasma Treated Wool Fibers by X-Ray Photoelectron Spectroscopy, in "Proc. 5th Int. Wool Text. Res. Conf ," vol. II, Aachen, 1975, pp. 44-53. |
Библиографическая ссылка |
Millard, M.M. , and Pavlath, A.E., Surface Analysis of Wool Fibers and Fiber Coatings by X-Ray Photoelectron Spectroscopy , Textile Res. J. 42, 460-463 (1972). |
Библиографическая ссылка |
Rivett, D.E., Evans, D.J., Leeder, J.D., and Rippon, J.A., Separation and Analysis of the Surface Lipids of the Wool Fibre, in "7th Int. Wool Text. Res. Conf. Abstracts," no. A-6, Tokyo, 1985. |
Библиографическая ссылка |
Rivett, D.E., Roxburgh, C.M., and Savige, W.E., Amino Acids and Peptides, New Products from Alkaline Treatments of Cystine and Cysteine, in "Proc. 3rd Int. Wool Text. Res. Conf.," vol. II, Paris, 1965, pp. 419-430. |
Библиографическая ссылка |
Roberts, M.W. , Photoelectron Spectroscopy and Surface Chemistry , Chem. in Britain 17, 510-514 (1981). |
Библиографическая ссылка |
Schneider, J.F., and Westley, J., Metabolic Interactions of Sulfur in Proteins, Thiosulfate and Cystine, J. Biol. Chem.244, 5735-5744 (1969). |
Библиографическая ссылка |
Scofield, J.H. , Hartree Slater Subshell Photoionisation Cross Sections at 1254 and 1487 eV, J. Electron Spertrosc. 8, 129-141 (1976). |
Библиографическая ссылка |
Siegbahn, K. , Nordling, C., Fahlman, A., Nordberg, R., Hamrin, K., Hedman, J., Johansson, G., Bergmark, R., Karlson, S.E., Lindgren, I., and Lindberg, B., ESCA. Atomic, Molecular and Solid State Structure Studied by Means of Electron Spectroscopy, Nova Acta Regiae Soc. Sci. Upsal. IV 20 (1967). |
Библиографическая ссылка |
Singer, S.J. , and Nicolson, G.L., The Fluid Mosaic Model of the Structure of Cell Membranes, Science 175, 720-731 (1972). |
Библиографическая ссылка |
Swift, J.A. , Minimum Depth Electron Probe X-Ray Microanalysis as a Means for Determining the Sulfur Content of the Human Hair Surface, Scanning 2, 83-88 ( 1979). |