| Автор | Smith, D. |
| Автор | Adams, N. G. |
| Дата выпуска | 1982 |
| dc.description | Recent laboratory measurements of positive ion/negative ion recombination coefficients at pressures below 8 torr have indicated that the coefficients increase more rapidly with pressure than expected on the basis of previous higher pressure data. These data, together with previous recombination coefficients obtained in the low pressure limit, have been used to redetermine the total effective binary recombination coefficients which are most appropriate to the stratosphere. These new values are almost a factor of two larger than our previous values and are, within error, in agreement with the values derived from in‐situ measurements of ion densities and ionization production rates. It is concluded that the new values are accurate to better than ±50% and can be used with confidence in calculations of stratosphere deionization rates. |
| Формат | application.pdf |
| Копирайт | Copyright 1982 by the American Geophysical Union. |
| Тема | GEOCHEMISTRY |
| Тема | Geochemistry: Chemistry of the atmosphere |
| Тема | ATMOSPHERIC PROCESSES |
| Тема | Meteorology: Ionic interactions and processes |
| Название | Ionic recombination in the stratosphere |
| Тип | article |
| DOI | 10.1029/GL009i009p01085 |
| Electronic ISSN | 1944-8007 |
| Print ISSN | 0094-8276 |
| Журнал | Geophysical Research Letters |
| Том | 9 |
| Первая страница | 1085 |
| Последняя страница | 1087 |
| Выпуск | 9 |
| Библиографическая ссылка | Arijs, E., P.Nevejans, P.Frederick, J.Ingels, Negative ion composition measurements in the stratosphere, Geophys.Res.Lett., 8, 121–124, 1981. |
| Библиографическая ссылка | Arnold, F., R.Fabian, G.Henschen, W.Joos, Stratospheric trace gas analysis from ions; H<sub>2</sub>O and HNO<sub>3</sub>, Planet.Space Sci., 28, 681–685, 1980. |
| Библиографическая ссылка | Arnold, F., G.Henschen, E. E.Ferguson, Mass spectrometric measurements of fractional ion abundances in the stratosphere ‐ positive ions, Planet.Space Sci., 29, 185–193, 1981. |
| Библиографическая ссылка | Bates, D. R., Mutual neutralisation coefficient in an ambient gas, J.Phys.B, 14, 4207–4212, 1981. |
| Библиографическая ссылка | Bates, D. R., I.Mendas, Ionic recombination in ambient gas. II Computer experiment with specific allowance for binary recombination, Proc. R.Soc.Lond., A359, 287–301, 1978. |
| Библиографическая ссылка | Church, M. J., D.Smith, Ionic recombination of atomic and molecular ions in flowing afterglow plasma, J.Phys.D., 11, 2199–2206, 1978. |
| Библиографическая ссылка | Flannery, M. R., Ionic recombination, Atomic Processes and ApplicationsP. G.Burke, B. L.Moiseiwitsch, 408–466, North‐Holland Publ. Co., 1976. |
| Библиографическая ссылка | Gardener, M. E., The recombination of ions in pure oxygen as a function of pressure and temperature, Phys.Rev., 53, 75–83, 1938. |
| Библиографическая ссылка | Mahan, B. J., Recombination of gaseous ions, Advances in Chemical Physics, 23I.Prigogine, S. A.Rice, 1–39, Wiley, 1973. |
| Библиографическая ссылка | Mahan, B. H., J. C.Person, Gaseous ion recombination rates, J.Chem.Phys., 40, 392–401, 1964. |
| Библиографическая ссылка | Olson, R. E., Absorbing‐sphere model for calculating ion‐ion recombination total cross‐sections, J.Chem.Phys., 56, 2979–2984, 1972. |
| Библиографическая ссылка | Rosen, J. M., D. J.Hofmann, Balloon‐borne measurements of electrical conductivity, mobility and the recombination coefficient, J.Geophys.Res., 86, 7406–7410, 1981. |
| Библиографическая ссылка | Sayers, J., Ionic recombination in air, Proc.Roy. Soc.(Lond)., A169, 83–101, 1938. |
| Библиографическая ссылка | Smith, D., N. G.Adams, Elementary plasma reactions of environmental interest, Topics in Current Chemistry, 89S.Veprek, M.Venugopalan, Springer‐Verlag, 1980. |
| Библиографическая ссылка | Smith, D., N. G.Adams, Studies of ion‐ion recombination using flowing afterglow plasmas, Ion‐Ion and Electron‐Ion CollisionsF.Brouillard, J.Wm.McGowan, Plenum, 1982. |
| Библиографическая ссылка | Smith, D., M. J.Church, Binary ion‐ion recombination coefficients determined in a flowing afterglow plasma, Int.J.Mass Spectrom. Ion. Phys., 19, 185–200, 1976. |
| Библиографическая ссылка | Smith, D., M. J.Church, Ion‐ion recombination rates in the Earth's atmosphere, Planet. Space Sci., 25, 433–439, 1977. |
| Библиографическая ссылка | Smith, D., N. G.Adams, A. G.Dean, M. J.Church, The application of Langmuir probes to the study of flowing afterglow plasmas, J. Phys. D., 8, 141–152, 1975. |
| Библиографическая ссылка | Smith, D., M. J.Church, T. M.Miller, Mutual neutralization of simple and clustered positive and negative ions, J. Chem.Phys., 68, 1224–1229, 1978. |
| Библиографическая ссылка | Smith, D., N. G.Adams, E.Alge, Ion‐ion mutual neutralization and ion‐neutral switching reacttions of some stratospheric ions, Planet. Space. Sci., 29, 449–454, 1981. |
| Библиографическая ссылка | Whitten, B. L., Wm.L.Morgan, J. N.Bardsley, Monte‐Carlo calculations of two and three body ionic recombination, J.Phys.B., 15, 319–326, 1982. |
| Библиографическая ссылка | , AGU, U.S. Standard Atmosphere, U.S. Government Printing Office, Washington D.C., 1976. |
| Библиографическая ссылка | Viggiano, A. A., F.Arnold, Extended sulfuric acid vapor concentration measurements in the stratosphere, Geophys.Res. Lett., 8, 583–586, 1981a. |
| Библиографическая ссылка | Viggiano, A. A., F.Arnold, The first height measurements of the negative ion composition of the stratosphere, Planet.Space Sci., 29, 895–906, 1981b. |
