Автор |
Hanson, D. R. |
Автор |
Ravishankara, A. R. |
Дата выпуска |
1991 |
dc.description |
We measured the first‐order loss rate coefficients for CF<sub>2</sub>O on solid surfaces, ice and HNO<sub>3</sub>‐treated ice, and on sulfuric acid solutions that coated the inside wall of a flow tube. We determined an upper limit for the uptake coefficient, γ, of ∼3×10<sup>−6</sup> for CF<sub>2</sub>O on ice and HNO<sub>3</sub>‐treated ice. A value for γ on a 60% (by weight) sulfuric acid solution of 3(+2/−3)× 10<sup>−6</sup> was measured and we observed a higher value over 40% acid, γ = 6×10<sup>−5</sup> (± 30%). The loss of CF<sub>2</sub>O on stratospheric particles is a very slow process and will be insignificant for events that occur on timescales of a year, such as the annual polar chlorine activation phenomena. |
Формат |
application.pdf |
Копирайт |
Copyright 1991 by the American Geophysical Union. |
Тема |
Atmospheric Composition and Structure |
Тема |
Atmospheric Composition and Structure: Middle atmosphere—composition and chemistry |
Тема |
Atmospheric Composition and Structure: Cloud physics and chemistry |
Тема |
Atmospheric Composition and Structure: Ion chemistry of the atmosphere |
Тема |
Atmospheric Processes |
Тема |
Meteorology and Atmospheric Dynamics: Atmospheric electricity |
Тема |
Meteorology and Atmospheric Dynamics: Mesoscale meteorology |
Тема |
Meteorology and Atmospheric Dynamics: Polar meteorology |
Название |
The loss of CF<sub>2</sub>O on ice, NAT, and sulfuric acid solutions |
Тип |
article |
DOI |
10.1029/91GL02093 |
Electronic ISSN |
1944-8007 |
Print ISSN |
0094-8276 |
Журнал |
Geophysical Research Letters |
Том |
18 |
Первая страница |
1699 |
Последняя страница |
1701 |
Аффилиация |
Hanson, D. R.; NOAA Aeronomy Lab, Boulder, Colorado and Cooperative Institute for Research in Environmental Sciences, Univ. of Colorado |
Аффилиация |
Ravishankara, A. R.; Also affiliated with Dept. of Chemistry and Biochemistry, Univ. of Colorado, Boulder, CO |
Выпуск |
9 |
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