Автор |
Dickens, Gerald R. |
Автор |
Quinby‐Hunt, Mary S. |
Дата выпуска |
1994 |
dc.description |
Experimental data are presented for methane hydrate stability conditions in seawater (S ≈ 33.5‰). For the pressure range of 2.75–10.0 MPa, at any given pressure, the dissociation temperature of mcthane hydrate is depressed by approximately −1.1°C relative to the pure methane‐pure water system. These experimental results are consistent with previously reported thermodynamic predictions and experimental results obtained with artificial seawater. Collectively these results provide a minimum constraint concerning depth ranges over which methane hydrate is stable in the oceanic environment. |
Формат |
application.pdf |
Копирайт |
Copyright 1994 by the American Geophysical Union. |
Тема |
BIOGEOSCIENCES |
Тема |
Nutrients and nutrient cycling |
Тема |
EXPLORATION GEOPHYSICS |
Тема |
Seismic methods |
Тема |
GEOCHEMISTRY |
Тема |
Marine geochemistry |
Тема |
MARINE GEOLOGY AND GEOPHYSICS |
Тема |
Marine seismics |
Тема |
Continental shelf and slope processes |
Тема |
OCEANOGRAPHY: GENERAL |
Тема |
Continental shelf and slope processes |
Тема |
Oceanography: General: Physical and chemical properties of sea water |
Тема |
OCEANOGRAPHY: BIOLOGICAL AND CHEMICAL |
Тема |
Marine organic chemistry |
Тема |
SEISMOLOGY |
Тема |
Seismic instruments and networks |
Название |
Methane hydrate stability in seawater |
Тип |
article |
DOI |
10.1029/94GL01858 |
Electronic ISSN |
1944-8007 |
Print ISSN |
0094-8276 |
Журнал |
Geophysical Research Letters |
Том |
21 |
Первая страница |
2115 |
Последняя страница |
2118 |
Выпуск |
19 |
Библиографическая ссылка |
Appenzeller, T., Fire and ice under the deep‐sea floor, Science, 252, 1790–1792, 1991. |
Библиографическая ссылка |
Barduhn, A. J., H. E.Towlson, Y. C.Hu, The properties of some new gas hydrates and their use in demineralizing sea water, AIChE J., 8, 176–183, 1962. |
Библиографическая ссылка |
Cande, S. C., R. B.Leslie, J. C.Parra, M.Hobart, Interaction between the Chile Ridge and Chile Trench: geophysical and geothermal evidence, J. Geophys. Res., 92, 495–520, 1987. |
Библиографическая ссылка |
Cha, S. B., H.Oaur, T. R.Wildeman, E. D.Sloan, A third‐surface effect on hydrate formation, J. Phys. Chem., 92, 6492–6494, 1988. |
Библиографическая ссылка |
Claypool, G. E., I. R.Kaplan, The origin and distribution of methane in marine sediments, Natural Gases in Marine Sediments, I. R.Kaplan, 94–139, Plenum Press, New York, 1974. |
Библиографическая ссылка |
deRoo, J. L., C. J.Peters, R. N.Lichtenthaler, G. A. M.Diepen, Occurrence of methane hydrate in saturated and unsaturated solutions of sodium chloride and water in dependence of temperature and pressure, AIChE J., 29, 651–657, 1983. |
Библиографическая ссылка |
Dholabhai, P. D., P.Englezos, N.Kalogerakis, P. R.Bishnoi, Equilibrium conditions for methane hydrate formation in aqueous mixed electrolyte solutions, Can. J. Chem. Eng., 69, 800–805, 1991. |
Библиографическая ссылка |
Englezos, P., P. R.Bishnoi, Prediction of gas hydrate formation conditions in aqueous electrolyte solutions, AIChE J., 34, 1718–1721, 1988. |
Библиографическая ссылка |
Holder, G. D., G.Gorbin, K. D.Papadopoulous, Thermodynamic and molecular properties of gas hydrates from mixtures containing methane, argon, and krypton, Ind. Eng. Chem. Fund., 19, 282–286, 1980. |
Библиографическая ссылка |
Hyndman, R. D., J. P.Foucher, M.Yamano, A.Fisher, Scientific Team of Ocean Drilling Program Leg 131, Deep sea bottom‐simulating‐reflectors: calibration of the base of the hydrate stability field as used for heat flow estimates, Earth Planet. Sci. Lett., 109, 289–301, 1992. |
Библиографическая ссылка |
Katz, D. L., D.Cornell, R.Kobayashi, F. H.Poetmann, J. A.Vary, J. R.Elenblass, C. F.Weinaug, Handbook of Natural Gas Engineering, 802, McGraw‐Hill, New York, 1959. |
Библиографическая ссылка |
Korvezee, A. E., A. P.Pieroen, On the enthalpy change on formation of a solid compound from a gaseous and a liquid component, Rec. Trav. Chim., 81, 385–394, 1962. |
Библиографическая ссылка |
Kvenvolden, K. A., Methane hydrates and global climate, Global Biogeochem. Cycles, 2, 221–229, 1988a. |
Библиографическая ссылка |
Kvenvolden, K. A., Methane hydrate‐a major reservoir of carbon in the shallow geosphere?, Chem. Geol., 71, 41–51, 1988b. |
Библиографическая ссылка |
Kvenvolden, K. A., Gas hydrates ‐ Geological perspective and global change, Rev. Geophys., 31, 173–187, 1993. |
Библиографическая ссылка |
Kvenvolden, K. A., A.Grantz, Gas hydrates of the Arctic Ocean region, The Arctic Ocean Region, A.Graritz, L.Johnson, J. F.Sweeney, 539–549, Geol. Soc. Am., Boulder, 1990. |
Библиографическая ссылка |
MacDonald, G. J., Role of methane clathrates in past and future climates, Clim. Change, 16, 247–281, 1990. |
Библиографическая ссылка |
Menton, P. D., W. R.Parrish, E. D.Sloan, Effect of inhibitors on hydrate formation, Ind. Eng. Chem. Proc. Des. Dev., 20, 399–401, 1981. |
Библиографическая ссылка |
Noaker, L. J., D. L.Katz, Gas hydrates of hydrogen sulfide‐methane mixtures, Trans. AIME, 201, 237–239, 1954. |
Библиографическая ссылка |
Nisbet, E. G., The end of the ice age, Can. J. Earth Sci., 27, 148–157, 1990. |
Библиографическая ссылка |
Paull, C. K., W.UsslerIII, Is the extent of glaciation limited by marine gas‐hydrates?, Geophys. Res Lett., 18, 432–434, 1991. |
Библиографическая ссылка |
Robinson, D. B., J. M.Hutton, Hydrate formation in systems containing methane, hydrogen sulfide, and carbon dioxide, J. Canad. Pet. Tech., 6, 6–9, 1967. |
Библиографическая ссылка |
Shipley, T. H., M. H.Houston, R. T.Buffler, P. J.Shaub, K. J.McMillen, J. W.Ladd, J. L.Worzel, Seismic reflection evidence for the widespread occurrence of possible gas‐hydrate horizons on continental slopes and rises, A.A.P.G. Bull., 63, 2204–2213, 1979. |
Библиографическая ссылка |
SloanJr., E. D., Clathrate Hydrates of Natural Gases, 641, Marcel Dekker, Inc., New York, 1990. |
Библиографическая ссылка |
van derWaals, J. H., J. C.Platteeuw, Clathrate solutions, Adv. Chem. Phys., 2, 1–57, 1959. |