Автор |
Olivero, J. J. |
Автор |
Stagat, R. W. |
Автор |
Green, A. E. S. |
Дата выпуска |
1972 |
dc.description |
We examine the consequences of electron impact on water vapor in terms of the microscopic details of excitation, dissociation, and ionization and combinations of these processes. Basic electron‐impact cross section data are assembled in many forms and are incorporated into semi‐analytic functions suitable for analysis with digital computers. Energy deposition in water vapor is discussed and the energy loss function is presented, along with the ‘electron volts per ion pair’ and the efficiencies of energy loss in various processes. We consider several applications of electron and water‐vapor interactions in the atmospheric sciences, in particular, H<sub>2</sub>O comets, aurora and airglow, and lightning. In general we find that, except in the case of lightning, other processes are more likely sources of H*, O*, and OH* emissions. |
Формат |
application.pdf |
Копирайт |
Copyright © 1972 by the American Geophysical Union. |
Тема |
COMPUTATIONAL GEOPHYSICS |
Тема |
Planetology: Atmospheres of planets |
Тема |
MARINE GEOLOGY AND GEOPHYSICS |
Тема |
Meteorology: Electrical phenomena |
Тема |
Meteorology: H₂O in the atmosphere (humidity, clouds, and precipitation) |
Тема |
Meteorology: Ionic interactions and processes |
Название |
Electron deposition in water vapor, with atmospheric applications |
Тип |
article |
DOI |
10.1029/JA077i025p04797 |
Electronic ISSN |
2156-2202 |
Print ISSN |
0148-0227 |
Журнал |
Journal of Geophysical Research |
Том |
77 |
Первая страница |
4797 |
Последняя страница |
4811 |
Выпуск |
25 |
Библиографическая ссылка |
Anderson, J. G., Rocket‐borne ultraviolet spectrometer measurement of OH resonance fluorescence with a diffusive transport model of mesospheric photochemistry, J. Geophys. Res., 76, 4634, 1971. |
Библиографическая ссылка |
Barth, C. A., Ultraviolet spectroscopy of planetsTech. Rep. 38–‐822Jet Propul. Lab., Calif. Inst. Technol, Pasadena, Calif., 1965. |
Библиографическая ссылка |
Berger, M. J., S. M.Seltzer, Tables of energylosses and ranges of electrons and positrons, Studies in Penetration of Charged Particles in Matter, Publ. 1133, 205Nat. Acad. Sci. Nat. Res. Counc, Washington, D. C., 1964. |
Библиографическая ссылка |
Buchel'nikova, N. S., Cross sections for the capture of slow electrons by O<sub>2</sub>. and H<sub>2</sub>O molecules and molecules of halogen compounds, Sov. Phys. JETP, 35, 783, 1959. |
Библиографическая ссылка |
Chamberlain, J. W., Physics of the Aurora and Airglow, 424, Academic, New York, 1961. |
Библиографическая ссылка |
Clark, T. A., B.Donn, W. M.Jackson, W. T.Sullivan III, N.Vandenberg, Search for microwave H<sub>2</sub>O emission in Comet Bennett (1969i), Astron. J., 76, 614, 1971. |
Библиографическая ссылка |
Claydon, C. R., G. A.Segal, H. S.Taylor, Theoretical interpretation of the optical and electron scattering spectra of H<sub>2</sub>O, J. Chem. Phys., 54, 3799, 1971. |
Библиографическая ссылка |
Compton, R. N., L. G.Christophorou, Negative‐ion formation in H<sub>2</sub>O and D<sub>2</sub>O, Phys. Rev., 154, 110, 1967. |
Библиографическая ссылка |
Dufay, F., Investigation of the spectra of lightning flashes, 2, Study of the spectrum in the violet and ultraviolet regions, Ann. Geophys., 5, 255, 1949. |
Библиографическая ссылка |
Fehsenfeld, F. C., E. E.Ferguson, Origin of water cluster ions in the D‐region, J. Geophys. Res., 74, 2217, 1969. |
Библиографическая ссылка |
Ferguson, E. E., F. C.Fehsenfeld, Water vapor ion cluster concentrations in the D‐region, J. Geophys. Res., 74, 5743, 1969. |
Библиографическая ссылка |
Green, A. E. S., S. K.Dutta, Semi‐empirical cross sections for electron impact, J. Geophys. Res., 72, 3933, 1967. |
Библиографическая ссылка |
Green, A. E. S., T.Sawada, Ionization cross sections and secondary electron distributions, J. Atmos. Terr. Phys., 1972. |
Библиографическая ссылка |
Green, A. E. S., J. J.Olivero, R. W.Stagal, Microdosimetry of low‐energy electrons, Proc. Biophys. Aspects Radiat. Qual. Symp, 79, , 1971. |
Библиографическая ссылка |
Hayakawa, G., Simultaneous dissociation and excitation of H<sub>2</sub>O molecule by electron impact, Proc. Phys. Math. Soc. Jap., 26, 78, 1944. |
Библиографическая ссылка |
Herzberg, G., Electronic Spectra of Polyatomic Molecules, 489–490 and p. 585, D. Van Nostrand, Princeton, N.J., 1966. |
Библиографическая ссылка |
Hunt, B. G., Photochemistry of ozone in a moist atmosphere, J. Geophys. Res., 71, 1385, 1966. |
Библиографическая ссылка |
Jusick, A. T., C. E.Watson, L. R.Peterson, A. E. S.Green, Electron impact cross sections for atmospheric species, 1, Helium, J. Geophys. Res., 72, 3943, 1967. |
Библиографическая ссылка |
Klots, C. E., Energy deposition mechanisms, Fundamental Processes in Radiation ChemistryP.Ausloos, 1, Interscience, New York, 1968. |
Библиографическая ссылка |
Lassettre, E. N., Inelastic scattering of electrons by atmospheric gases, Can. J. Chem., 47, 1733, 1969. |
Библиографическая ссылка |
Lassettre, E. N., E. R.White, Electronic collision cross sections of water vapor, Sci. Rep12, 1–53Dep. Chem., Ohio State Univ. Res. Found, Columbus, Ohio, 1958. |
Библиографическая ссылка |
Lawrence, G. M., The dissociative excitation of some oxygen containing molecules: Lifetimes and electron impact cross sections, Phys. Rev. A, 2, 397, 1970. |
Библиографическая ссылка |
Leovy, C. B., Atmospheric ozone: An analytic model for photochemistry in the presence of water vapor, J. Geophys. Res., 74, 417, 1969. |
Библиографическая ссылка |
Mann, M. M., A.Hustrulid, J. T.Tate, The ionization and dissociation of water vapor and ammonia by electron impact, Phys. Rev., 58, 340, 1940. |
Библиографическая ссылка |
Mastenbrook, H. J., Water vapor distribution in the stratosphere and high troposphere, J. Atmos. Sci., 25, 299, 1968. |
Библиографическая ссылка |
McKinnon, D., H. W.Morewood, Water vapor distribution in the lower stratosphere over North and South America, J. Atmos. Sci., 27, 483, 1970. |
Библиографическая ссылка |
Metzger, P. H., G. R.Cook, On the continuous absorption, photoionization, and fluorescence of H<sub>2</sub>O, NH<sub>3</sub>, CH<sub>4</sub>, C<sub>2</sub>H<sub>2</sub>, and C<sub>2</sub>H<sub>6</sub>in the 600‐to‐1000A region, J. Chem. Phys., 41, 622, 1964. |
Библиографическая ссылка |
Miller, R. E., W. G.Fastie, R. C.Isler, Rocket studies of far‐ultraviolet radiation in an aurora, J. Geophys. Res., 73, 3353, 1968. |
Библиографическая ссылка |
Miller, K. J., S. R.Miekzarek, M.Krauss, Energy surface and generalized oscillator strength of the <sup>1</sup>A” Rydberg state of H<sub>2</sub>O, J. Chem. Phys., 51, 26, 1969. |
Библиографическая ссылка |
Muschlitz, E. E., T. L.Bailey, Negative ion formation in hydrogen peroxide and water vapor, The perhydroxide ion, J. Phys. Chem., 60, 681, 1956. |
Библиографическая ссылка |
Narcisi, R. S., On water cluster ions in the ionospheric D‐region, Space Res., 9, 1969. |
Библиографическая ссылка |
Narcisi, R. S., A. D.Bailey, Mass spectrometric measurement of positive ions at altitudes from 64 to 112 kilometers, J. Geophys. Res., 70, 3687, 1965. |
Библиографическая ссылка |
Nicolet, M., Ozone and hydrogen reactions, Ann. Geophys., 26, 531, 1970. |
Библиографическая ссылка |
Niira, K., On the excitation of H<sub>2</sub>O molecule by impact of fast electron, J. Phys. Soc. Jap., 4, 230, 1949. |
Библиографическая ссылка |
Opal, C. B., E. C.Beaty, W. K.Peterson, Tables of energy and angular distributions of electrons ejected from simple gases by electron impactRep. 108Joint Inst. Lab. Astrophys., Univ. of Colorado, Boulder, Colorado, 1971. |
Библиографическая ссылка |
Peterson, L. R., A. E. S.Green, The relation between ionization yields, cross sections and loss functions, Proc. Phys. Soc. London, Ser., lB, 1131, 1968. |
Библиографическая ссылка |
Schultz, G. J., Excitation and negative ions in H<sub>2</sub>O, J. Chem. Phys., 33, 1661, 1960. |
Библиографическая ссылка |
Schutten, J., F. J.deHeer, H. R.Moustafa, A. J. H.Boerboon, J.Kistemaker, Grossand partial‐ionization cross sections for electrons on water vapor in the energy range 0.1–20 kev, J. Chem. Phys., 44, 3924, 1966. |
Библиографическая ссылка |
Skerbele, A., V. D.Meyer, E. N.Lassettre, Relative intensities of two Rydberg transitions in the electron‐impact spectrum of water, J. Chem. Phys., 43, 817, 1965. |
Библиографическая ссылка |
Stolarski, R. S., A. E. S.Green, Calculations of auroral intensities from electron impact, J. Geophys. Res., 72, 3967, 1967. |
Библиографическая ссылка |
Stolarski, R. S., V. A.Dulock, C. E.Watson, A. E. S.Green, Electron impact cross sections for atmospheric species, 2, Molecular nitrogen, J. Geophys. Res., 72, 3953, 1967. |
Библиографическая ссылка |
Trajmar, S., W.Williams, A.Kupperman, Detection and identification of triplet states in H<sub>2</sub>O by electron impact, J. Chem. Phys., 54, 2274, 1971. |
Библиографическая ссылка |
Watanabe, K., A. S.Jursa, Absorption and photoionization cross sections of H<sub>2</sub>O and H<sub>2</sub>S, J. Chem. Phys., 41, 1650, 1964. |
Библиографическая ссылка |
Watanabe, K., M.Zelikoff, Absorption coefficients of water vapor in the vacuum ultraviolet, J. Opt. Soc. Amer., 43, 753, 1953. |
Библиографическая ссылка |
Watson, C. E., V. A.DulockJr., R. S.Stolarski, A. E. S.Green, Electron impact cross sections for atmospheric species, 3, Molecular oxygen, J. Geophys. Res., 72, 3961, 1967. |
Библиографическая ссылка |
Vroom, D. A., F. J.deHeer, Production of excited hydrogen atoms by impact of fast electrons on water vapor, J. Chem. Phys., 50, 1883, 1969. |
Библиографическая ссылка |
Zander, R., M.Bottema, Water vapor in the stratosphere, J. Geophys. Res., 72, 5749, 1967. |