| Автор | Addison, C. C. |
| Автор | Pulham, R. J. |
| Дата выпуска | 1972 |
| dc.description | The stoicheiometry and rates of reaction of liquid sodium with the oxides Fe3O4, Co3O4, and NiO have been studied by measuring the quantity of sodium consumed over a range of reaction times and temperatures. The nickel oxide reaction becomes rapid above 150°, and the sodium consumed corresponds precisely to complete reduction to nickel metal. Reaction of Fe3O4 is slow below 250°; reduction to metallic iron is only 80% complete at 250°, and this is attributed to ternary oxide formation. The oxide Co3O4 reacts rapidly below 120°, and explosively above this temperature. Reduction to cobalt metal is about 90% complete at 120°. |
| Формат | application.pdf |
| Издатель | Royal Society of Chemistry |
| Название | Reactions of liquid sodium with transition-metal oxides. Part V. The oxides Fe3O4, Co3O4, and NiO; stoicheometry and reaction rates |
| Тип | research-article |
| DOI | 10.1039/DT9720001020 |
| Electronic ISSN | 1364-5447 |
| Print ISSN | 1472-7773 |
| Журнал | Journal of the Chemical Society, Dalton Transactions |
| Первая страница | 1020 |
| Последняя страница | 1022 |
| Выпуск | 10 |
