Synthesis of hydrido-bis(acetylide) complexes of rhodium and the molecular structures of mer-trans-[Rh(PMe3)3(H)(CCPh)2] and mer-trans-[{Rh(dmpe)(H)(CCSiMe3)2}2(µ-dmpe)](dmpe = Me2PCH2CH2PMe2)
Chow, Pauline; Zargarian, David; Taylor, Nicholas J.; Marder, Todd B.
Журнал:
Journal of the Chemical Society, Chemical Communications
Дата:
1989
Аннотация:
Complexes of the form mer-trans-[Rh(PMe3)3(H)(C.tbd6;CR)2] and mer-trans-[{Rh(dmpe)(H)(C.tbd6;CR)2}2(µ-dmpe)] have been prepared by oxidative addition of HC.tbd6;CR to [Rh(PMe3)4(C.tbd6;CR)] and [Rh(dmpe)2Me] species, respectively; the molecular structures of mer-trans-[Rh(PMe3)3(H)(C.tbd6;CPh)2] and mer-trans-[{Rh(dmpe)(H)(C.tbd6;CSiMe3)2}2(µ-dmpe)](dmpe = Me2PCH2CH2PMe2) have been determined by single crystal X-ray diffraction studies.
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