Автор | Chow, Pauline |
Автор | Zargarian, David |
Автор | Taylor, Nicholas J. |
Автор | Marder, Todd B. |
Дата выпуска | 1989 |
dc.description | Complexes of the form mer-trans-[Rh(PMe3)3(H)(C.tbd6;CR)2] and mer-trans-[{Rh(dmpe)(H)(C.tbd6;CR)2}2(µ-dmpe)] have been prepared by oxidative addition of HC.tbd6;CR to [Rh(PMe3)4(C.tbd6;CR)] and [Rh(dmpe)2Me] species, respectively; the molecular structures of mer-trans-[Rh(PMe3)3(H)(C.tbd6;CPh)2] and mer-trans-[{Rh(dmpe)(H)(C.tbd6;CSiMe3)2}2(µ-dmpe)](dmpe = Me2PCH2CH2PMe2) have been determined by single crystal X-ray diffraction studies. |
Формат | application.pdf |
Издатель | Royal Society of Chemistry |
Название | Synthesis of hydrido-bis(acetylide) complexes of rhodium and the molecular structures of mer-trans-[Rh(PMe3)3(H)(CCPh)2] and mer-trans-[{Rh(dmpe)(H)(CCSiMe3)2}2(µ-dmpe)](dmpe = Me2PCH2CH2PMe2) |
Тип | research-article |
DOI | 10.1039/C39890001545 |
Print ISSN | 0022-4936 |
Журнал | Journal of the Chemical Society, Chemical Communications |
Первая страница | 1545 |
Последняя страница | 1547 |
Выпуск | 20 |