Mechanistic insight into the lanthanide (iii) salt catalysed monoacylation of symmetrical diols from structural modelsElectronic supplementary information (ESI) available: experimental details. See http://www.rsc.org/suppdata/cc/b3/b308171k/
Clarke, Paul A.; Arnold, Polly L.; Smith, Martin A.; Natrajan, Louise S.; Wilson, Claire; Chan, Chuen; Clarke Paul A.; School of Chemistry, University of Nottingham; Arnold Polly L.; School of Chemistry, University of Nottingham; Smith Martin A.; School of Chemistry, University of Nottingham; Natrajan Louise S.; School of Chemistry, University of Nottingham; Wilson Claire; School of Chemistry, University of Nottingham; Chan Chuen; Medicinal Chemistry, GlaxoSmithKline
Журнал:
Chemical Communications
Дата:
2003
Аннотация:
Model studies are presented that suggest the mechanism of the lanthanide(iii) salt catalysed mono acylation of symmetrical diols proceeds via chelation of the diol and the anhydride to the lanthanide salt, followed by an â intramolecularâ acyl transfer.
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