Dioxygen activation by a dinuclear nickel thiolate complex: structural characterization of the ligand oxidized productElectronic supplementary information (ESI) available: Fig. S1: 1H NMR spectrum of 2. Fig. S2: Electronic spectrum showing conversion of 1 to 2. See http://www.rsc.org/suppdata/cc/b2/b211395n/
Harrop, Todd C.; Olmstead, Marilyn M.; Mascharak, Pradip K.; Harrop Todd C.; Department of Chemistry and Biochemistry, University of California; Olmstead Marilyn M.; Department of Chemistry, University of California; Mascharak Pradip K.; Department of Chemistry and Biochemistry, University of California
Журнал:
Chemical Communications
Дата:
2003
Аннотация:
A (μ-SR)2-nickel(ii) dimer derived from a ligand with carboxamido nitrogen and thiolato sulfur donors reacts with O2 to afford an oxidized product in which phenyl groups of the ligand frames are oxidized to nickel-bound phenolates.
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