| Автор | Darcos, Vincent |
| Автор | Griffith, Kirsten |
| Автор | Sallenave, Xavier |
| Автор | Desvergne, Jean-Pierre |
| Автор | Guyard-Duhayon, Carine |
| Автор | Hasenknopf, Bernold |
| Автор | Bassani, Dario M. |
| Дата выпуска | 2003 |
| dc.description | The use of supramolecular catalysis to control the photoinduced dimerization of styrene, cinnamate, and stilbene chromophores is reported. The strategy employs the formation of a 2 â ¶ 1 supramolecular assembly in the presence of 5,5-dihexylbarbituric acid (DHB). A 3- to 10-fold increase in dimerization efficiency is observed in its presence, concomitant with accrued selectivity for the syn photodimers. The origin of the regioselectivity in the presence of DHB is discussed in terms of topochemical control within the supramolecular architecture. |
| Формат | application.pdf |
| Издатель | Royal Society of Chemistry |
| Название | Supramolecular control of [2 + 2] photodimerization via hydrogen bondingThis paper is dedicated to Professor Fred Lewis on the event of his 60th birthday. |
| Тип | research-article |
| DOI | 10.1039/b307525g |
| Electronic ISSN | 1474-9092 |
| Print ISSN | 1474-905X |
| Журнал | Photochemical & Photobiological Sciences |
| Том | 2 |
| Первая страница | 1152 |
| Последняя страница | 1161 |
| Аффилиация | Darcos Vincent; Groupe de Chimie Supramoléculaire, Biomimétisme et Nanosciences, Université Bordeaux I |
| Аффилиация | Griffith Kirsten; Groupe de Chimie Supramoléculaire, Biomimétisme et Nanosciences, Université Bordeaux I |
| Аффилиация | Sallenave Xavier; Groupe de Chimie Supramoléculaire, Biomimétisme et Nanosciences, Université Bordeaux I |
| Аффилиация | Desvergne Jean-Pierre; Groupe de Chimie Supramoléculaire, Biomimétisme et Nanosciences, Université Bordeaux I |
| Аффилиация | Guyard-Duhayon Carine; Laboratoire de Chimie Inorganique et Matériaux Moléculaires, Université Pierre et Marie Curie |
| Аффилиация | Hasenknopf Bernold; Laboratoire de Chimie Inorganique et Matériaux Moléculaires, Université Pierre et Marie Curie |
| Аффилиация | Bassani Dario M.; Groupe de Chimie Supramoléculaire, Biomimétisme et Nanosciences, Université Bordeaux I |
| Выпуск | 11 |
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