| Автор | Griffiths, T. R. |
| Автор | Scarrow, R. K. |
| Дата выпуска | 1970 |
| dc.description | The chloro-nickel(II) complexes obtained in dimethyl sulphoxide (DMSO) are described, viz., the octahedral complexes [NiCl(DMSO)5]<sup>+</sup> and [NiCl2(DMSO)4]<sup>0</sup> and the tetrahedral complexes [NiCl3(DMSO)]<sup>â </sup> and NiCl4 <sup>2â </sup>. It is shown that the tetrahedral species produced on warming a solution of NiCl2 is [NiCl3(DMSO)]<sup>â </sup>, not NiCl4 <sup>2â </sup> as previously claimed. The effect of temperature upon the various equilibria existing in solution at different Cl : Ni mole ratios is discussed and the effect of cation variation is noted. For the equilibrium [NiCl2(DMSO)4]<sup>0</sup>+ Cl<sup>â </sup> â [NiCl3(DMSO)]<sup>â </sup>+ 3DMSO, Î H was calculated to be +13·3 ± 0·3 kcal. mole<sup>â 1</sup>. |
| Формат | application.pdf |
| Издатель | Royal Society of Chemistry |
| Название | Influence of temperature and concentration upon nickel(II) chloride interactions in dimethyl sulphoxide |
| Тип | research-article |
| DOI | 10.1039/J19700000827 |
| Print ISSN | 0022-4944 |
| Журнал | Journal of the Chemical Society A: Inorganic, Physical, Theoretical |
| Первая страница | 827 |
| Последняя страница | 833 |
