1,1â ²-Bis(trimethylsilylseleno)ferrocene in cluster synthesis: a redox active surface on a copperâ selenide coreElectronic supplementary information (ESI) available: cyclic voltammograms for 1 and 2, <sup>1</sup>H NMR spectrum for 1. See http://www.rsc.org/suppdata/cc/b0/b010023o/ Dedicated to Dr Arthur J. Carty on the occasion of his 60th birthday.
Wallbank, Andrew I.; Corrigan, John F.; Wallbank Andrew I.; Department of Chemistry, The University of Western Ontario; Corrigan John F.; Department of Chemistry, The University of Western Ontario
Журнал:
Chemical Communications
Дата:
2001
Аннотация:
1,1⠲-Bis(trimethylsilylseleno)ferrocene 1 has been prepared from the reaction of [1,1⠲-Fe(η<sup>5</sup>-C5H4SeLi)2 (TMEDA)] and ClSiMe3 in good yield. The reactive silyl groups on 1 are used as a driving force for the synthesis of [Cu8{Fe(η<sup>5</sup>-C5H4Se) 2}4(PPh2Et)4] 2, a cluster possessing four peripheral ferrocenyl moieties.
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