The pyrethrins and related compounds. Part XVIII. Insecticidal 2,2-dimethylcyclopropanecarboxylates with new unsaturated 3-substituents
Elliott, Michael; Janes, Norman F.; Pulman, David A.
Журнал:
Journal of the Chemical Society, Perkin Transactions 1
Дата:
1974
Аннотация:
Fifty new esters related to the insecticide bioresmethrin [5-benzyl-3-furylmethyl (1R,3R)-2,2-dimethyl-3-(2-methylprop-1-enyl) cyclopropanecarboxylate], having various groups in place of the 2-methylprop-1-enyl side chain, have been synthesised. cis- and trans-3-Formyl-2,2-dimethylcyclopropanecarboxylic esters are obtained by ozonolysis of the corresponding chrysanthemates. Wittig and other reactions with these esters then give the required products. 5-Benzyl-3-furylmethyl esters are obtained by transesterification or via acids obtained by cleavage of t-butyl esters under mild conditions.
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