| Автор | Elliott, Michael |
| Автор | Janes, Norman F. |
| Автор | Pulman, David A. |
| Дата выпуска | 1974 |
| dc.description | Fifty new esters related to the insecticide bioresmethrin [5-benzyl-3-furylmethyl (1R,3R)-2,2-dimethyl-3-(2-methylprop-1-enyl) cyclopropanecarboxylate], having various groups in place of the 2-methylprop-1-enyl side chain, have been synthesised. cis- and trans-3-Formyl-2,2-dimethylcyclopropanecarboxylic esters are obtained by ozonolysis of the corresponding chrysanthemates. Wittig and other reactions with these esters then give the required products. 5-Benzyl-3-furylmethyl esters are obtained by transesterification or via acids obtained by cleavage of t-butyl esters under mild conditions. |
| Формат | application.pdf |
| Издатель | Royal Society of Chemistry |
| Название | The pyrethrins and related compounds. Part XVIII. Insecticidal 2,2-dimethylcyclopropanecarboxylates with new unsaturated 3-substituents |
| Тип | research-article |
| DOI | 10.1039/P19740002470 |
| Electronic ISSN | 1364-5463 |
| Print ISSN | 0300-922X |
| Журнал | Journal of the Chemical Society, Perkin Transactions 1 |
| Первая страница | 2470 |
| Последняя страница | 2474 |