Co-chelation of a scorpion-shaped carboxylate ligand and phenanthroline lead to a 2-D interpenetratively tubular architecture
Cao, Xin-Yi; Zhang, Jian; Cheng, Jian-Kai; Kang, Yao; Yao, Yuan-Gen; Cao Xin-Yi; State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, The Chinese Academy of Sciences; Zhang Jian; State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, The Chinese Academy of Sciences; Cheng Jian-Kai; State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, The Chinese Academy of Sciences; Kang Yao; State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, The Chinese Academy of Sciences; Yao Yuan-Gen; State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, The Chinese Academy of Sciences
Журнал:
CrystEngComm
Дата:
2004
Аннотация:
A novel zinc coordination supramolecular complex, {[Zn3(OABDC)2(phen)3]·2H2O}n, with an open-ended nanotube architecture based on a nano-sized tetranuclear Zn4(OABDC)4 metallacycle repeating unit, is strategically designed and synthesized using a unique scorpion-shaped carboxylate ligand (5-oxyacetate isophthalic acid = H3OABDC) and phenanthroline.
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