Absolute oscillator strength of the (0.0) band of the gamma system of nitric oxide by the hook method
A Pery-Thorne; F P Banfield; A Pery-Thorne; Imperial Coll., London, UK; F P Banfield; Imperial Coll., London, UK
Журнал:
Journal of Physics B: Atomic and Molecular Physics
Дата:
1970-07-01
Аннотация:
The hook method has been adapted for molecular spectra to allow a determination of the absolute oscillator strength of a band from measurements on a single hook near the band head. For the A<sup>2</sup> Sigma <sup>+</sup>-X<sup>2</sup>II system of nitric oxide, the value f<sub>00</sub>=(3.64+or-0.05)*10<sup>-4</sup> was obtained, in good agreement with previous measurements on the integrated absorption at high pressures. The behaviour of f<sub>00</sub> as a function of pressure was investigated at pressures up to 7 atm of nitric oxide and 35 atm of argon, but no variation was found. The relation between f<sub>00</sub> and the latest experimental value for the lifetime of the v'=0 vibrational level is discussed, using recent measurements for the variation of electronic transition moment with r centroid; the inconsistencies between these three sets of measurement prove to be considerably larger than the apparent experimental errors.
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