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Автор A Pery-Thorne
Автор F P Banfield
Дата выпуска 1970-07-01
dc.description The hook method has been adapted for molecular spectra to allow a determination of the absolute oscillator strength of a band from measurements on a single hook near the band head. For the A<sup>2</sup> Sigma <sup>+</sup>-X<sup>2</sup>II system of nitric oxide, the value f<sub>00</sub>=(3.64+or-0.05)*10<sup>-4</sup> was obtained, in good agreement with previous measurements on the integrated absorption at high pressures. The behaviour of f<sub>00</sub> as a function of pressure was investigated at pressures up to 7 atm of nitric oxide and 35 atm of argon, but no variation was found. The relation between f<sub>00</sub> and the latest experimental value for the lifetime of the v'=0 vibrational level is discussed, using recent measurements for the variation of electronic transition moment with r centroid; the inconsistencies between these three sets of measurement prove to be considerably larger than the apparent experimental errors.
Формат application.pdf
Издатель Institute of Physics Publishing
Название Absolute oscillator strength of the (0.0) band of the gamma system of nitric oxide by the hook method
Тип paper
DOI 10.1088/0022-3700/3/7/017
Print ISSN 0022-3700
Журнал Journal of Physics B: Atomic and Molecular Physics
Том 3
Первая страница 1011
Последняя страница 1019
Аффилиация A Pery-Thorne; Imperial Coll., London, UK
Аффилиация F P Banfield; Imperial Coll., London, UK
Выпуск 7

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