The structure of superionic compounds by powder neutron diffraction. I. Cation distribution in α-AgI
A F Wright; B E F Fender; A F Wright; Inst. Laue-Langevin, Grenoble, France; B E F Fender; Inst. Laue-Langevin, Grenoble, France
Журнал:
Journal of Physics C: Solid State Physics
Дата:
1977-07-14
Аннотация:
A powder neutron diffraction study of alpha -AgI has been carried out at several temperatures between 180 degrees C and 450 degrees C. The results do not support the widely quoted model for the distribution of silver ions originally proposed by Strock (1934-36) but instead indicate the silver ions are confined to the twelve tetrahedral sites of the body-centred cubic structure. Remarkably large temperature factors are observed and it is postulated that there is a large anharmonic contribution to the thermal vibrations arising from a reduced energy barrier in the direction of the octahedral sites.
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