Автор |
A F Wright |
Автор |
B E F Fender |
Дата выпуска |
1977-07-14 |
dc.description |
A powder neutron diffraction study of alpha -AgI has been carried out at several temperatures between 180 degrees C and 450 degrees C. The results do not support the widely quoted model for the distribution of silver ions originally proposed by Strock (1934-36) but instead indicate the silver ions are confined to the twelve tetrahedral sites of the body-centred cubic structure. Remarkably large temperature factors are observed and it is postulated that there is a large anharmonic contribution to the thermal vibrations arising from a reduced energy barrier in the direction of the octahedral sites. |
Формат |
application.pdf |
Издатель |
Institute of Physics Publishing |
Название |
The structure of superionic compounds by powder neutron diffraction. I. Cation distribution in α-AgI |
Тип |
paper |
DOI |
10.1088/0022-3719/10/13/003 |
Print ISSN |
0022-3719 |
Журнал |
Journal of Physics C: Solid State Physics |
Том |
10 |
Первая страница |
2261 |
Последняя страница |
2267 |
Аффилиация |
A F Wright; Inst. Laue-Langevin, Grenoble, France |
Аффилиация |
B E F Fender; Inst. Laue-Langevin, Grenoble, France |
Выпуск |
13 |