Автор |
S Clough |
Автор |
A Heidemann |
Автор |
M N J Paley |
Автор |
J -B Suck |
Дата выпуска |
1980-12-30 |
dc.description |
Methyl tunnel splittings and torsion frequencies have been measured by inelastic neutron scattering for seven acetates. The parameters of the hindering potential V<sub>3</sub> cos 3 phi +V<sub>6</sub> cos 6 phi where phi is the methyl rotation angle, were determined from the spectra. The ratio V<sub>6</sub>/V<sub>3</sub> is similar (about 0.15) for six of the samples though sodium acetate appears anomalous. The dependence of this ratio on the form of interatomic potentials is discussed. |
Формат |
application.pdf |
Издатель |
Institute of Physics Publishing |
Название |
Methyl tunnelling and torsion in acetates: the shape of hindering potentials |
Тип |
paper |
DOI |
10.1088/0022-3719/13/36/013 |
Print ISSN |
0022-3719 |
Журнал |
Journal of Physics C: Solid State Physics |
Том |
13 |
Первая страница |
6599 |
Последняя страница |
6606 |
Аффилиация |
S Clough; Dept. of Phys., Univ. of Nottingham, Nottingham, UK |
Аффилиация |
A Heidemann; Dept. of Phys., Univ. of Nottingham, Nottingham, UK |
Аффилиация |
M N J Paley; Dept. of Phys., Univ. of Nottingham, Nottingham, UK |
Аффилиация |
J -B Suck; Dept. of Phys., Univ. of Nottingham, Nottingham, UK |
Выпуск |
36 |