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Автор S Clough
Автор A Heidemann
Автор M N J Paley
Автор J -B Suck
Дата выпуска 1980-12-30
dc.description Methyl tunnel splittings and torsion frequencies have been measured by inelastic neutron scattering for seven acetates. The parameters of the hindering potential V<sub>3</sub> cos 3 phi +V<sub>6</sub> cos 6 phi where phi is the methyl rotation angle, were determined from the spectra. The ratio V<sub>6</sub>/V<sub>3</sub> is similar (about 0.15) for six of the samples though sodium acetate appears anomalous. The dependence of this ratio on the form of interatomic potentials is discussed.
Формат application.pdf
Издатель Institute of Physics Publishing
Название Methyl tunnelling and torsion in acetates: the shape of hindering potentials
Тип paper
DOI 10.1088/0022-3719/13/36/013
Print ISSN 0022-3719
Журнал Journal of Physics C: Solid State Physics
Том 13
Первая страница 6599
Последняя страница 6606
Аффилиация S Clough; Dept. of Phys., Univ. of Nottingham, Nottingham, UK
Аффилиация A Heidemann; Dept. of Phys., Univ. of Nottingham, Nottingham, UK
Аффилиация M N J Paley; Dept. of Phys., Univ. of Nottingham, Nottingham, UK
Аффилиация J -B Suck; Dept. of Phys., Univ. of Nottingham, Nottingham, UK
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