A sensitive nuclear quadrupole resonance spectrometer for 2-60 MHz
F N H Robinson; F N H Robinson; Clarendon Lab., Univ. of Oxford, Oxford, UK
Журнал:
Journal of Physics E: Scientific Instruments
Дата:
1982-08-01
Аннотация:
The paper describes the design, construction and performance of a continuous-wave spectrometer for use at temperatures between 77K and 80 degrees C. The limiting sensitivity for chlorine resonances with narrow lines is 1 mu mol and compounds of molar volume up to 10<sup>4</sup> cm<sup>3</sup> can be studied. The corresponding figures for nitrogen resonances are 300 mu mol and 10<sup>3</sup> cm<sup>3</sup>. The continuous tuning range with a single coil is 2.5:1 and the resolution is a few PPM. It uses bisymmetric Zeeman modulation, there are no critical adjustments and no elaborate extra equipment is required.
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