Order-disorder transformation in Co<sub>30</sub>Pt<sub>70</sub> alloy: evidence of wetting from the antiphase boundaries
C Leroux; A Loiseau; M C Cadeville; D Broddin; G Van Tendeloo; C Leroux; Antwerp Univ., Belgium; A Loiseau; Antwerp Univ., Belgium; M C Cadeville; Antwerp Univ., Belgium; D Broddin; Antwerp Univ., Belgium; G Van Tendeloo; Antwerp Univ., Belgium
Журнал:
Journal of Physics: Condensed Matter
Дата:
1990-04-16
Аннотация:
A study of the order-disorder L1<sub>2</sub> to A1 transformation near a congruent point of the Co-Pt phase diagram is presented. This work was performed by combining in situ transmission electron microscopy observations, resistivity measurements carried out in conditions near thermodynamic equilibrium and high-resolution imaging on quenched samples. Resistivity measurements display three characteristic temperatures: 994 K, 1020 K and 1032 K. The evolution of the microstructure with temperature at different heating rates was followed in dark field images, until the order-disorder temperature was reached. It was found that at temperatures above 994 K ( approximately=40 K below T<sub>c</sub>), the antiphase boundaries (APB) undergo a structural change; the phenomenon becomes more pronounced as the temperature increases. High-resolution images of modified APB show thin layers of disordered phase in the core of these APB. This can be described as a wetting of the antiphase boundaries by the disordered phase. Above 1020 K, up to 1032 K, a second mechanism is superimposed; the disordering occurs through a nucleation, growth and coarsening of disordered regions inside the ordered domains. This nucleation and growth process starts at the beginning of the two-phase region (1020 K). These results are in excellent agreement with those from cluster variation method calculations performed by Kikuchi and Cahn (1979) and Finel and co-workers (1990).
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