Автор |
C Leroux |
Автор |
A Loiseau |
Автор |
M C Cadeville |
Автор |
D Broddin |
Автор |
G Van Tendeloo |
Дата выпуска |
1990-04-16 |
dc.description |
A study of the order-disorder L1<sub>2</sub> to A1 transformation near a congruent point of the Co-Pt phase diagram is presented. This work was performed by combining in situ transmission electron microscopy observations, resistivity measurements carried out in conditions near thermodynamic equilibrium and high-resolution imaging on quenched samples. Resistivity measurements display three characteristic temperatures: 994 K, 1020 K and 1032 K. The evolution of the microstructure with temperature at different heating rates was followed in dark field images, until the order-disorder temperature was reached. It was found that at temperatures above 994 K ( approximately=40 K below T<sub>c</sub>), the antiphase boundaries (APB) undergo a structural change; the phenomenon becomes more pronounced as the temperature increases. High-resolution images of modified APB show thin layers of disordered phase in the core of these APB. This can be described as a wetting of the antiphase boundaries by the disordered phase. Above 1020 K, up to 1032 K, a second mechanism is superimposed; the disordering occurs through a nucleation, growth and coarsening of disordered regions inside the ordered domains. This nucleation and growth process starts at the beginning of the two-phase region (1020 K). These results are in excellent agreement with those from cluster variation method calculations performed by Kikuchi and Cahn (1979) and Finel and co-workers (1990). |
Формат |
application.pdf |
Издатель |
Institute of Physics Publishing |
Название |
Order-disorder transformation in Co<sub>30</sub>Pt<sub>70</sub> alloy: evidence of wetting from the antiphase boundaries |
Тип |
paper |
DOI |
10.1088/0953-8984/2/15/005 |
Electronic ISSN |
1361-648X |
Print ISSN |
0953-8984 |
Журнал |
Journal of Physics: Condensed Matter |
Том |
2 |
Первая страница |
3479 |
Последняя страница |
3495 |
Аффилиация |
C Leroux; Antwerp Univ., Belgium |
Аффилиация |
A Loiseau; Antwerp Univ., Belgium |
Аффилиация |
M C Cadeville; Antwerp Univ., Belgium |
Аффилиация |
D Broddin; Antwerp Univ., Belgium |
Аффилиация |
G Van Tendeloo; Antwerp Univ., Belgium |
Выпуск |
15 |