An NMR study on the liquid caesium-oxygen system: the state of oxygen and ionic association in the metallic regime
Y Tsuchiya; E F W Seymours; G A Styles; Y Tsuchiya; Dept. of Phys., Warwick Univ., Coventry, UK; E F W Seymours; Dept. of Phys., Warwick Univ., Coventry, UK; G A Styles; Dept. of Phys., Warwick Univ., Coventry, UK
Журнал:
Journal of Physics: Condensed Matter
Дата:
1994-05-23
Аннотация:
The liquid caesium-oxygen system in the metallic regime has been investigated by the NMR technique. Measurements were made of the Knight shift for both <sup>133</sup>Cs and <sup>17</sup>O nuclei, and the nuclear relaxation time, T<sub>1</sub>, for the latter. The Knight shift for <sup>133</sup>Cs nuclei decreases almost linearly up to 25 at.% of O and further decreases with a steeper slope to the value in Cs<sub>2</sub>O, while the shift for <sup>17</sup>O nuclei is almost independent of the composition up to 21 at.%. The analysis of T<sub>1</sub> suggests that the gradient of the electrostatic field coupled with the nuclear quadrupole moment of <sup>17</sup>O is also insensitive to the composition. The results are discussed with particular reference to the state of the O atoms and possible ionic association in the liquid Cs-O system in the metallic regime.
485.7Кб