Автор |
Y Tsuchiya |
Автор |
E F W Seymours |
Автор |
G A Styles |
Дата выпуска |
1994-05-23 |
dc.description |
The liquid caesium-oxygen system in the metallic regime has been investigated by the NMR technique. Measurements were made of the Knight shift for both <sup>133</sup>Cs and <sup>17</sup>O nuclei, and the nuclear relaxation time, T<sub>1</sub>, for the latter. The Knight shift for <sup>133</sup>Cs nuclei decreases almost linearly up to 25 at.% of O and further decreases with a steeper slope to the value in Cs<sub>2</sub>O, while the shift for <sup>17</sup>O nuclei is almost independent of the composition up to 21 at.%. The analysis of T<sub>1</sub> suggests that the gradient of the electrostatic field coupled with the nuclear quadrupole moment of <sup>17</sup>O is also insensitive to the composition. The results are discussed with particular reference to the state of the O atoms and possible ionic association in the liquid Cs-O system in the metallic regime. |
Формат |
application.pdf |
Издатель |
Institute of Physics Publishing |
Название |
An NMR study on the liquid caesium-oxygen system: the state of oxygen and ionic association in the metallic regime |
Тип |
paper |
DOI |
10.1088/0953-8984/6/21/013 |
Electronic ISSN |
1361-648X |
Print ISSN |
0953-8984 |
Журнал |
Journal of Physics: Condensed Matter |
Том |
6 |
Первая страница |
3889 |
Последняя страница |
3898 |
Аффилиация |
Y Tsuchiya; Dept. of Phys., Warwick Univ., Coventry, UK |
Аффилиация |
E F W Seymours; Dept. of Phys., Warwick Univ., Coventry, UK |
Аффилиация |
G A Styles; Dept. of Phys., Warwick Univ., Coventry, UK |
Выпуск |
21 |