| Автор | S Ansell |
| Автор | R H Tromp |
| Автор | G W Neilson |
| Дата выпуска | 1995-02-20 |
| dc.description | Neutron diffraction experiments were carried out on isotopically labelled copper chloride (CuCl<sub>2</sub>) salt in a 4 molal aqueous solution. The first- and second-order isotopic difference methods were used to obtain structural information on the hydration structure of the Cu<sup>2+</sup> and Cl<sup>-</sup> ions and to calculate the pair distribution functions g<sub>CuCl</sub>(r) and g<sub>ClCl</sub>(r) The results confirm the highly distorted nearest-neighbour coordination of Cu<sup>2+</sup>, and give direct evidence that Cu-Cl contacts exist over a range 2.3<or=r (AA)<or=3.5. Analysis of g<sub>ClCl</sub>(r) gives consistent information with that of g<sub>CuCl</sub>(r) and shows that direct contacts also exist between Cl<sup>-</sup> ions, over the range 2.8<or=r (AA)<or=4.2. |
| Формат | application.pdf |
| Издатель | Institute of Physics Publishing |
| Название | The solute and aquaion structure in a concentrated aqueous solution of copper(II) chloride |
| Тип | paper |
| DOI | 10.1088/0953-8984/7/8/002 |
| Electronic ISSN | 1361-648X |
| Print ISSN | 0953-8984 |
| Журнал | Journal of Physics: Condensed Matter |
| Том | 7 |
| Первая страница | 1513 |
| Последняя страница | 1524 |
| Аффилиация | S Ansell; H.H. Wills Phys. Lab., Bristol Univ., UK |
| Аффилиация | R H Tromp; H.H. Wills Phys. Lab., Bristol Univ., UK |
| Аффилиация | G W Neilson; H.H. Wills Phys. Lab., Bristol Univ., UK |
| Выпуск | 8 |
