A stop-scan interferometer used for time-resolved FTIR emission spectroscopy
P Biggs; G Hancock; D E Heard; R P Wayne; P Biggs; Phys. Chem. Lab., Oxford Centre for Appl. Kinetics, UK; G Hancock; Phys. Chem. Lab., Oxford Centre for Appl. Kinetics, UK; D E Heard; Phys. Chem. Lab., Oxford Centre for Appl. Kinetics, UK; R P Wayne; Phys. Chem. Lab., Oxford Centre for Appl. Kinetics, UK
Журнал:
Measurement Science and Technology
Дата:
1990-07-01
Аннотация:
The authors describe how a low-cost teaching interferometer has been modified for use as a time-resolved instrument to study the infrared vibrational chemiluminescence of the products from atom-radical reactions and molecular photodissociations. This technique allows the entire temporal evolution of the emission spectrum to be obtained from a single interferometric scan, with spectral and temporal resolutions of 2 cm<sup>-1</sup> and 3 mu s respectively. Illustrative results are given for discharge-flow studies of laser initiated atom-radical reactions, where product emission from highly vibrationally excited CO<sub>2</sub> and HF is observed, and for emission from vibrationally excited products of the infrared multiple-photon dissociation of halocarbon molecules.
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