Автор |
P Biggs |
Автор |
G Hancock |
Автор |
D E Heard |
Автор |
R P Wayne |
Дата выпуска |
1990-07-01 |
dc.description |
The authors describe how a low-cost teaching interferometer has been modified for use as a time-resolved instrument to study the infrared vibrational chemiluminescence of the products from atom-radical reactions and molecular photodissociations. This technique allows the entire temporal evolution of the emission spectrum to be obtained from a single interferometric scan, with spectral and temporal resolutions of 2 cm<sup>-1</sup> and 3 mu s respectively. Illustrative results are given for discharge-flow studies of laser initiated atom-radical reactions, where product emission from highly vibrationally excited CO<sub>2</sub> and HF is observed, and for emission from vibrationally excited products of the infrared multiple-photon dissociation of halocarbon molecules. |
Формат |
application.pdf |
Издатель |
Institute of Physics Publishing |
Название |
A stop-scan interferometer used for time-resolved FTIR emission spectroscopy |
Тип |
paper |
DOI |
10.1088/0957-0233/1/7/016 |
Electronic ISSN |
1361-6501 |
Print ISSN |
0957-0233 |
Журнал |
Measurement Science and Technology |
Том |
1 |
Первая страница |
630 |
Последняя страница |
636 |
Аффилиация |
P Biggs; Phys. Chem. Lab., Oxford Centre for Appl. Kinetics, UK |
Аффилиация |
G Hancock; Phys. Chem. Lab., Oxford Centre for Appl. Kinetics, UK |
Аффилиация |
D E Heard; Phys. Chem. Lab., Oxford Centre for Appl. Kinetics, UK |
Аффилиация |
R P Wayne; Phys. Chem. Lab., Oxford Centre for Appl. Kinetics, UK |
Выпуск |
7 |