Formation of cobalt silicides as a buried layer in silicon using high energy heavy ion irradiation
Chakraborty, B R; Halder, S K; Karar, N; Kabiraj, D; Avasthi, D K; Chakraborty, B R; National Physical Laboratory, Dr K S Krishnan Road, New Delhi, 110012, India;; Halder, S K; National Physical Laboratory, Dr K S Krishnan Road, New Delhi, 110012, India; Karar, N; National Physical Laboratory, Dr K S Krishnan Road, New Delhi, 110012, India; Kabiraj, D; Nuclear Science Centre, Aruna Asaf Ali Road, New Delhi, 110064, India; Avasthi, D K; Nuclear Science Centre, Aruna Asaf Ali Road, New Delhi, 110064, India
Журнал:
Journal of Physics D: Applied Physics
Дата:
2005-08-21
Аннотация:
A multilayer heterostructure of Si(50 nm)/Co(50 nm)/Si(50 nm)/Si⟨ 100⟩ was prepared by an e-beam evaporation technique under UHV conditions and it was then subjected to irradiation by 120 MeV Au<sup>+</sup> ions with fluence varying between 10<sup>13</sup> and 10<sup>14</sup> ions cm<sup>−2</sup>. No external thermal treatments were used. Secondary ion mass spectrometry was used in the depth profile mode, which indicated a monotonic increase in the mixing width with fluence at the first interface of Si/Co. Depth profile analysis suggested major changes in the preferential sputtering rates of Co at the interface indicating formation of silicides. Further investigation by x-ray diffraction confirmed the formation of different phases of cobalt silicides, Co<sub>2</sub>Si, CoSi and CoSi<sub>2</sub>, as a buried layer, while the Raman spectroscopy showed broad peaks near 325 and 725 cm<sup>−1</sup>, which are characteristic of the CoSi<sub>2</sub> phase. The above work suggests that swift heavy ion irradiation can be advantageously used for interconnect related buried layer silicide formation at room temperature avoiding thermal annealing.
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