| Автор | Mogi, Iwao |
| Автор | Watanabe, Kazuo |
| Дата выпуска | 2006-05-31 |
| dc.description | Polyaniline films were prepared by electropolymerization under a magnetic field of 5T parallel (+5T) or antiparallel (−5T) to the faradaic currents. They were used as a modified electrode and their chiral properties were examined for L-3-(3,4-dihydroxyphenyl)alanine (L-DOPA), L-ascorbic acid (L-AA) and D-isoascorbic acid (D-AA) by cyclic voltammetry. The redox currents of L-DOPA on the +5T-film electrode were smaller than those on the −5T-film electrode, and the results for racemic mixture of L- and D-DOPA were the same on the two electrodes. The oxidation current of L-AA on the +5T-film electrode was larger than that on the −5T-film electrode, and the result for D-AA was opposite. These facts demonstrate that the two electrodes have the opposite chirality each other and possess the ability of chiral recognition. |
| Формат | application.pdf |
| Издатель | Institute of Physics Publishing |
| Копирайт | © 2006 Elsevier Ltd |
| Название | Chiral recognition of magneto-electropolymerized polyaniline film electrodes |
| Тип | paper |
| DOI | 10.1016/j.stam.2006.01.007 |
| Electronic ISSN | 1878-5514 |
| Print ISSN | 1468-6996 |
| Журнал | Science and Technology of Advanced Materials |
| Том | 7 |
| Первая страница | 342 |
| Последняя страница | 345 |
| Аффилиация | Mogi, Iwao; |
| Аффилиация | Watanabe, Kazuo; Institute for Materials Research, Tohoku University, 2-1-1 Katahira, Aoba-ku, Sendai 980-8577, Japan |
| Выпуск | 4 |
