Автор |
Sexton, M. J. |
Автор |
Forbes, L. K. |
Дата выпуска |
1996 |
dc.description |
This paper investigates the effect of linear control as applied to an exothermic Sal?nikov chemical reaction. It will demonstrate how the control reduces the amplitude of the naturally occurring oscillations in temperature. However, in different parameter regions, this is not the case; that is, the reaction has desirable behaviour without control. A mathematical and numerical analysis of the system will be presented. Steady-state solutions are examined, and the emergence of limit cycles will be shown via the Hopf condition. The conditions under which oscillatory behaviour is not observed will be identified. When oscillatory behaviour is detected, the region to which it is confined will be described. Finally, an example is given of a nonlinear control, which ensures that the system will only portray stable behaviour, and under certain parameter constraints can eliminate oscillations entirely. |
Формат |
application.pdf |
Издатель |
Journals Oxford Ltd |
Копирайт |
Copyright Taylor and Francis Group, LLC |
Название |
An exothermic chemical reaction with linear feedback control |
Тип |
research-article |
DOI |
10.1080/02681119608806225 |
Electronic ISSN |
1465-3389 |
Print ISSN |
0268-1110 |
Журнал |
Dynamics and Stability of Systems |
Том |
11 |
Первая страница |
219 |
Последняя страница |
238 |
Аффилиация |
Sexton, M. J.; Department of Mathematics, University of Queensland |
Аффилиация |
Forbes, L. K.; Department of Mathematics, University of Queensland |
Выпуск |
3 |
Библиографическая ссылка |
Aris, R. and Amundson, N. R. 1958. An analysis of chemical reactor-stability and control II. Chemical Engineering Science, 7: 132–147. |
Библиографическая ссылка |
Bailey, J. E. 1973. Periodic operation of chemical reactors: a review. Chemical Engineering Communications, 1: 111–124. |
Библиографическая ссылка |
Bailey, J. E., Horn, F. J. M. and Lin, R. C. 1971. Cyclic operation of reaction systems: effects of heat and mass transfer resistance. American Institute of Chemical Engineers Journal, 17: 818–825. |
Библиографическая ссылка |
Ball, R. and Gray, B. F. 1995. Transient thermal behaviour of the hydration of 2,3-epoxy-l-propanol in a continuously stirred tank reactor. Industrial and Engineering Chemical Research, 34: 3726–3736. |
Библиографическая ссылка |
Carr, T. W. and Schwartz, I. B. 1994. Controlling unstable steady states using system parameter variation and control duration. Physical Review E, E 50: 3410–3415. |
Библиографическая ссылка |
Coppersthwaite, D. P.,, Griffiths, J. F. and Gray, B. G. 1991. Oscillations in the reaction: experimental measurements and numerical simulation. Journal of Physical Chemistry, 95: 6961–6967. |
Библиографическая ссылка |
Douglas, J. M. and Rippin, D. W. T. 1996. Unsteady state process operation. Chemical Engineering Science, 21: 305–315. |
Библиографическая ссылка |
Epstein, I. R.,, Kustin, K.,, De Kepper, P. and Orbán, M. 1983. Oscillating chemical reactions. Scientific American, 248: 96–108. |
Библиографическая ссылка |
Forbes, L. K. 1990. Limit-cycle behaviour in a model chemical reaction: the Sal'nikov thermokinetic oscillator. Proceedings of the Royal Society of London A, 430: 641–651. |
Библиографическая ссылка |
Forbes, L. K. and Holmes, C. A. 1990. Limit-cycle behaviour in a model chemical reaction: the cubic autocatalator. Journal of Engineering Mathematics, 24: 179–189. |
Библиографическая ссылка |
Forbes, L. K.,, Myerscough, M. R. and Gray, B. 1991. On the presence of limit-cycles in a model exothermic chemical reaction: Sal'nikov's oscillator with two temperature-dependent reaction rates. Proceedings of the Royal Society of London A, 435: 591–604. |
Библиографическая ссылка |
Gray, P. and Griffiths, J. 1989. Thermokinetic combustion oscillations as an alternative to thermal explosion. Combustion And Flame, 78: 87–98. |
Библиографическая ссылка |
Guckenheimer, J. and Holmes, P. 1983. Nonlinear Oscillations, Dynamical Systems, and Bifurcations of Vector Fields, Vol. 42, New York: Springer. Applied Mathematical Sciences |
Библиографическая ссылка |
Jordan, D. W. and Smith, P. 1979. Nonlinear Ordinary Differential Equations, Oxford: Clarendon Press. |
Библиографическая ссылка |
Melsa, J. L. and Schultz, D. G. 1969. Linear Control Systems, New York: McGraw-Hill. |
Библиографическая ссылка |
Newitt, D. M. and Thornes, L. S. 1937. The oxidation of propane part 1. The products of the slow oxidation at atmospheric and at reduced pressures. Journal of the Chemical Society, : 1656–1665. |
Библиографическая ссылка |
Ott, E.,, Grebogi, C. and Yorke, J. A. 1990. Controlling chaos. Physical Review Letters, 64: 1196–1199. |
Библиографическая ссылка |
Petrov, V.,, Peng, B. and Showalter, K. 1992. A map-based algorithm for controlling low-dimensional chaos. Journal of Chemical Physics, 96: 7506–7513. |
Библиографическая ссылка |
Sal'nikov, I. Ye. 1949. Contribution to the theory of the periodic homogeneous chemical reactions. Zhurnal Fizicheskoi Khimii, 23: 258–272. |
Библиографическая ссылка |
Gray, P. and Scott, S. K. 1990. Chemical Oscillations and Instabilities: Non-linear Chemical Kinetics, New York: Clarendon Press. |
Библиографическая ссылка |
Sexton, M. J. and Forbes, L. K. 1996. A note on oscillations in a simple model of a chemical reaction. Journal of the Australian Mathematical Society Series B, 37: 451–457. |
Библиографическая ссылка |
Shinbrot, T.,, Grebogi, C., Ott, E. and Yorke, J. A. 1993. Using small perturbations to control chaos. Nature, 363: 411–417. |
Библиографическая ссылка |
Sidhu, H. S., Forbes, L. K. and Gray, B. F. 1996. Periodically forced hydrocarbon oxidation reaction in a CSTR. International Journal of Bifurcation & Chaos, 363 |
Библиографическая ссылка |
Sinčić, D. and Bailey, J. E. 1977. Pathological dynamic behavior of forced periodic chemical processes. Chemical Engineering Science, 32: 281–286. |
Библиографическая ссылка |
Sterman, L. E. and Ydstie, B. E. 1990. The steady-state process with periodic operations. Chemical Engineering Science, 45: 721–736. |
Библиографическая ссылка |
Tyson, J. 1969. The Belousov-Zhabotinskii reaction, Vol. 10, Springer. Lecture Notes in Biomathematics |
Библиографическая ссылка |
Wilson, H. D. and Rinker, R. G. 1982. Concentration forcing in ammonia synthesis?I. Chemical Engineering Science, 37: 343–355. |
Библиографическая ссылка |
Yang, C. H. and Gray, B. F. 1969. On the slow oxidation of hydrocarbons and cool flames. Journal of Physical Chemistry, 73: 3395–3406. |