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Автор Netxel, Danial A.
Автор Turner, Thomas F.
Дата выпуска 1990
dc.description ABSTRACTMany physicochemical properties of bitumens must be known in order to mathematically model and simulate the processes used for the recovery of bitumen from tar sands. One fundamental property is the temperature dependence of viscosity. This property determines the heat transfer and flow characteristics of a bitumen through a porous media.A method has been developed whereby the viscosity of a tar sand bitumen at any temperature can be calculated from nuclear magnetic resonance parameters. The method is semiempirical but is based upon some fundamental theoretical concepts for molecular mobility and intermolecular interactions. Using this method, the viscosities of three United States tar sand bitumens have been correlated to the weighted average spin-spin relaxation rates for the semiliquid, solidlike mobile, and solidlike rigid phases of the bitumens. The results indicate that bitumens with a high viscosity have a greater amount of solidlike rigid phase and lesser amounts of solidlike mobile and semiliquid phases than do the bitumens with low viscosity. It is also shown that the viscosity of a tar sand bitumen over a 100 degree temperature range can be determined from a single NMR experiment conducted near room temperature.
Формат application.pdf
Издатель Taylor & Francis Group
Копирайт Copyright Taylor and Francis Group, LLC
Название A CORRRELATION OF UNITED STATES TAR BAHD BITUMEN VISCOSITIES WITH EMR SPECTROSCOPIC PARAMETERS
Тип research-article
DOI 10.1080/08843759008915931
Print ISSN 0884-3759
Журнал Fuel Science and Technology International
Том 8
Первая страница 379
Последняя страница 403
Аффилиация Netxel, Danial A.; Western Reserch Institute
Аффилиация Turner, Thomas F.; Western Reserch Institute
Выпуск 4

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