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Автор peters*, Robert W.
Автор Ku, Young
Дата выпуска 1988
dc.description ABSTRACTIndustrial vastevaters generated in the electroplating and metal finishing industries typically contain toxic heavy metals. Depending on their origin, these wastewaters may also contain chelating agents, such as EDTA, NTA, citrate, tartrate, and gluconic acid. Although the major effect of complexation is an increase in the solubility of complexed metal ions, significant changes in the precipitation kinetics and particle size distribution may also contribute to the observed precipitation behavior.This paper addresses the effect of a weak complexing agent, tartrate, on the removal of zinc and cadmium using both hydroxide and sulfide treatment. Results are presented on the removal of heavy metals from synthetic plating wastewaters. Poor zinc removals were observed in the presence of tartrate, particularly when larger filter pore sizes were employed. The results suggest that tartrate severely hinders both zinc hydroxide and zinc sulfide precipitation, resulting in the formation of very fine precipitates; this was confirmed when no zinc removal occurred even with a settling time of 30 min. For removal of cadmium, virtually no change in residual cadmium concentration was observed in the presence of tartrate (compared to the case of no complexing agents present) due to the formation of low-stability complexes.
Формат application.pdf
Издатель Taylor & Francis Group
Копирайт Copyright Taylor and Francis Group, LLC
Название THE EFFECT OF TARTRATE, A WEAK COMPLEXING AGENT, ON THE REMOVAL OF HEAVY METALS BY SULFIDE AND HYDROXIDE PRECIPITATION
Тип research-article
DOI 10.1080/02726358808906515
Electronic ISSN 1548-0046
Print ISSN 0272-6351
Журнал Particulate Science and Technology
Том 6
Первая страница 421
Последняя страница 439
Аффилиация peters*, Robert W.; Environmental Engineering Department, School of Civil Engineering, Purdue University
Аффилиация Ku, Young; Environmental Engineering Department, School of Civil Engineering, Purdue University
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