| Автор | Nogami, Takashi |
| Автор | Tsuda, Minoru |
| Автор | Ishida, Takayuki |
| Автор | Kurono, Sadamu |
| Автор | Ohashi, Mamoru |
| Дата выпуска | 1993 |
| dc.description | AbstractBenzyne was found to add to C<sub>60</sub> in good yield to give C<sub>60</sub>(C<sub>6</sub>H<sub>4</sub>)<sub>n</sub> (n=1−4). Typical Diels-Alder dienes were also found to add to C<sub>60</sub> under thermally mild conditions. Adducts of C<sub>60</sub> with 2,3-dimethylbutadiene, cyclopentadiene, hexa-chlorocyclopentadiene, 1,3-diphenylisobenzofuran, and anthracene were obtained. Further reactions of these products such as elimination and autooxidation reactions were investigated. Addition reaction of dichlorocarbene to C<sub>60</sub> gave C<sub>61</sub>Cl<sub>2</sub>. Oxidation of C<sub>60</sub> with m-chloroperbenzoic acid gave C<sub>60</sub>O<sub>n</sub>(n=1, 2). All of the products were isolated by means of HPLC and characterized by mass spectroscopy. |
| Формат | application.pdf |
| Издатель | Taylor & Francis Group |
| Копирайт | Copyright Taylor and Francis Group, LLC |
| Название | Addition Reactions of Benzyne, Dienes, Dichlorocarbene, and Oxygen to C<sub>60</sub> |
| Тип | research-article |
| DOI | 10.1080/15363839308011896 |
| Print ISSN | 1064-122X |
| Журнал | Fullerene Science and Technology |
| Том | 1 |
| Первая страница | 275 |
| Последняя страница | 285 |
| Аффилиация | Nogami, Takashi; Department of Applied Physics and Chemistry, The University of Electro-Communications |
| Аффилиация | Tsuda, Minoru; Department of Applied Physics and Chemistry, The University of Electro-Communications |
| Аффилиация | Ishida, Takayuki; Department of Applied Physics and Chemistry, The University of Electro-Communications |
| Аффилиация | Kurono, Sadamu; Department of Applied Physics and Chemistry, The University of Electro-Communications |
| Аффилиация | Ohashi, Mamoru; Department of Applied Physics and Chemistry, The University of Electro-Communications |
| Выпуск | 3 |
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