A Study of the Addition of Alkylamines and Hydrazine to Fullerenes
Seshadri, Ram; Govindraj, A.; Rao, C. N. R.; Seshadri, Ram; Solid State and Structural Chemistry Unit & CSIR Centre of excellence in Chemistry Indian Institute of Science Bangalore; Govindraj, A.; Solid State and Structural Chemistry Unit & CSIR Centre of excellence in Chemistry Indian Institute of Science Bangalore; Rao, C. N. R.; Solid State and Structural Chemistry Unit & CSIR Centre of excellence in Chemistry Indian Institute of Science Bangalore
Журнал:
Fullerene Science and Technology
Дата:
1993
Аннотация:
AbstractA 1:1 monoadduct of 1-aminobutane with C<sub>60</sub>, C<sub>60</sub>(H)(n-C<sub>4</sub>H<sub>9</sub>NH), has been characterized by mass spectrometry, infrared spectroscopy and other techniques. Addition of 1,4-diaminobutane to C<sub>60</sub> gives rise to a 1:2 adduct of the diamine with C<sub>60</sub>, while hydrazine hydrate gives multiple addition products. Under conditions of diimide reduction, C<sub>60</sub> gives products resulting from the addition of hydrazine units as well as reduction.
323.7Кб