AbstractVarious “living” polymers were grafted onto C₆₀ The number of arms of the so obtained “star” molecules can be controlled by stoechiometry and/or by varying the reactivity of the carbanion on the “living” chain against a double bond on the C₆₀. Even the oxanion of “living” polyethylenoxide is able to add onto the reactive double bonds on C₆₀. In some conditions, the carbanions present on these alkaline salts of grafted fullerenes becomes able to initiate anionic polymerization of vinyl monomers. Using “living” poly(phenylvinylsulfoxide) as a precursor polymer for PA, polyacetylene chains could be attached to the fullerene.