| Автор | Carraher, Charles E. |
| Автор | Jambaya, Leonard M. |
| Дата выпуска | 1974 |
| dc.description | AbstractThe following tentative identifications are made from the study of variations in pH and substituted hydroquinones in the synthesis of zirconium polyethers: active species for aqueous solution systems, CP<sub>2</sub>Zr<sup>2+</sup> and RO η active species for interfacial systems, Cp<sub>2</sub> ZrCl<sub>2</sub> and R-OH with reaction occurring near the interface or in the organic phase. Yield increases as stirring rate increases throughout the stirring range of 13,000 to 24,500 rpm. Decent yields can also be obtained utilizing “inverse interfacial” systems where the Cp<sub>2</sub> ZrCl<sub>2</sub> is originally contained in water and the diol and added base in the organic layer. No product is found utilizing organic solution systems. |
| Формат | application.pdf |
| Издатель | Taylor & Francis Group |
| Копирайт | Copyright Taylor and Francis Group, LLC |
| Название | Reaction Species in the Aqueous Solution and Interfacial Synthesis of Zirconium Polyethers |
| Тип | research-article |
| DOI | 10.1080/00222337408068628 |
| Print ISSN | 0022-233X |
| Журнал | Journal of Macromolecular Science: Part A - Chemistry |
| Том | 8 |
| Первая страница | 1249 |
| Последняя страница | 1259 |
| Аффилиация | Carraher, Charles E.; Department of Chemistry, University of South Dakota |
| Аффилиация | Jambaya, Leonard M.; Department of Chemistry, University of South Dakota |
| Выпуск | 7 |
| Библиографическая ссылка | Carraher, C. and Jambaya, L. 1974. Angew. Makromol. Chem., 39: 41 |
| Библиографическая ссылка | Carraher, C. and Nordin, R. 1973. Makromol. Chem., 164: 87 |
| Библиографическая ссылка | Millich, F. and Carraher, C., eds. 1974. Interfacial Synthesis, New York: Dekker. |
| Библиографическая ссылка | Carraher, C. 1972. Inorg. Mecromol. Rev., 1: 271 |
| Библиографическая ссылка | Carraher, C. and Bajah, S. 1973. Polymer, 14: 42 |
| Библиографическая ссылка | Carraher, C. 1973. Angew. Makromol. Chem., 28: 145 |
| Библиографическая ссылка | Carraher, C. 1969. J. Chem. Educ., 46: 314 |
| Библиографическая ссылка | Andra, K. 1967. Z. Chem., 7: 318 |
| Библиографическая ссылка | Calderazzo, F. 1969. Organometallic Chem. Rev., B-5: 547 |
| Библиографическая ссылка | Doyle, G. and Tobias, R. 1968. Inorg. Chem., 7: 2484 |
| Библиографическая ссылка | Abichandiain, C. and Jatkar, S. 1938. J. Indian Inst. Sci., 21A: 417 |
| Библиографическая ссылка | Millich, F. and Carraher, C. 1969. J. Polym. Sci., A-1, 7: 2669 |
| Библиографическая ссылка | Long, F. and Ballinger, P. 1960. J. Amer. Chem. Soc., 82: 795 |
| Библиографическая ссылка | Smirhova, O., Khasan, El Ali, Losev, I. and Kolesnikov, G. 1965. Vysokomol. Soedin., 7: 503 |
| Библиографическая ссылка | Morgan, P. 1963. Condensation Polymers: By Interfacial and Solution Techniques, New York: Wiley. |
