| Автор | Kim, Yun-Hi |
| Автор | Kwon, Soon-Ki |
| Автор | Gal, Yeong-Soon |
| Автор | Choi, Sam-Kwon |
| Дата выпуска | 1992 |
| dc.description | AbstractFilms of poly(dipropargylsilane derivatives) were easily prepared by solvent casting. The resulting red-black films were relatively flexible and ductile. By doping with electron acceptors, the electrical conductivity increased up to the order of 10<sup>−1</sup>-10<sup>0</sup> S/cm. The activation energy for the conduction of doped film was 4 kcal/mol. The change in Raman, IR, and UV-visible spectra by doping suggests electron transfer from the poly(dipropargylsilane derivatives) to the dopant, leading to the formation of polaron. It also was observed that doping with I<sub>2</sub> drastically destroys the crystallinity of the polymer. |
| Формат | application.pdf |
| Издатель | Taylor & Francis Group |
| Копирайт | Copyright Taylor and Francis Group, LLC |
| Название | Electrical Conductivity and Physical Properties of Poly(Dipropargylsilane Derivatives) Doped with Electron Acceptors |
| Тип | research-article |
| DOI | 10.1080/10101329208052184 |
| Electronic ISSN | 1520-5738 |
| Print ISSN | 1060-1325 |
| Журнал | Journal of Macromolecular Science, Part A |
| Том | 29 |
| Первая страница | 589 |
| Последняя страница | 597 |
| Аффилиация | Kim, Yun-Hi; Department of Chemistry, Korea Advanced Institute of Science and Technology |
| Аффилиация | Kwon, Soon-Ki; Department of Polymer Science and Engineering, Kyeongsang National University |
| Аффилиация | Gal, Yeong-Soon; Composite Material Laboratory, Agency for Defense Development |
| Аффилиация | Choi, Sam-Kwon; Department of Chemistry, Korea Advanced Institute of Science and Technology |
| Выпуск | 7 |
| Библиографическая ссылка | Chien, J. C. W. 1984. Polyacetylene, New York: Academic. |
| Библиографическая ссылка | Masuda, T. and Higashmura, T. 1987. Adv. Polym. Sci., 81: 121 |
| Библиографическая ссылка | Skothein, T. A. 1986. Handbook of Conducting Polymers, New York: Dekker. |
| Библиографическая ссылка | Gibson, H. W., Baily, F. C., Epstein, A. J., Rommelamanm, H., Kaplan, S., Harbour, J., Yang, X. Q., Tanner, D. B. and Pochan, J. M. 1983. J. Am. Chem. Soc., 105: 4417 |
| Библиографическая ссылка | Kim, Y. H., Gal, Y. S., Kim, U. Y. and Choi, S. K. 1988. Macromolecules, 21: 1991 |
| Библиографическая ссылка | Chiang, C. K., Park, Y. W., Heeger, A. J., Shirakawa, H., Louis, E. J. and MacDiarmid, A. G. 1978. J. Chem. Phys., 69: 5098 |
| Библиографическая ссылка | Kise, H., Sugihara, M. and He, F. F. 1985. J. Appl. Polym. Sci., 30: 1113 |
| Библиографическая ссылка | Hsu, S. L., Signorelli, A. S., Pez, G. P. and Baughman, R. H. 1978. J. Chem. Phys., 69: 106 |
| Библиографическая ссылка | Shrakawa, H., Ito, T. and Ikeda, S. 1973. Polym. J., 4: 460 |
| Библиографическая ссылка | Lefrant, S., Lichtmann, L. S., Temkin, H. and Fitchen, D. B. 1979. Solid State Commun., 29: 191 |
| Библиографическая ссылка | Harada, I., Furukawa, Y., Tasumi, M., Shirakawa, H. and Ikeda, S. 1980. Chem. Lett., : 267 |
