Synthesis, Characterisation and Reactions of Some Coordination Compounds of Trichloro(Cyclopentadienyl)-Titanium (IV)
Pathak, Ashish K.; Mittal, Anuj K.; Shukla, P. R.; Pathak, Ashish K.; Chemistry Department, Lucknow University; Mittal, Anuj K.; Chemistry Department, Lucknow University; Shukla, P. R.; Chemistry Department, Lucknow University
Журнал:
Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry
Дата:
1995
Аннотация:
AbstractSome new ionic complexes of trichloro(cyclopentadienyl)titanium(IV) with N<sub>2</sub>S<sub>2</sub> and S<sub>2</sub>O<sub>2</sub> donor ligands derived from o-aminobenzenethiol have been synthesised. These complexes have been subjected to cyclisation resulting in macrocyclic complexes and secondary ligand addition reactions in order to study their effect on the coordination behaviour of the central titanium atom. The ligands, their complexes as well as reaction products were characterised using various spectro-chemical techniques. These complexes probably acquire octahedral geometries by planar coordination through four donor sites of the ligands, one axial position through the cyclopentadienyl group and the other through one chlorine atom.
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