| Автор | Wong, Chiu Ming |
| Автор | Ho, Tse-Lok |
| Дата выпуска | 1974 |
| dc.description | AbstractThe classical route to acetylenes from ketones involves the formation of gem-dichlorides or vinyl chlorides followed by elimination of hydrogen chloride with alkali hydroxides or amides.<sup>1</sup> The use of these latter reagents is evidently incompatible with compounds having other functional groups which are sensitive to strong bases. A need to preserve a carboxylic ester present in the same molecule in which a methyl ketone is to be transformed into the ethynyl moiety led us to investigate the modification of the dehydrochlorination process, and we wish to communicate our preliminary findings. |
| Формат | application.pdf |
| Издатель | Taylor & Francis Group |
| Копирайт | Copyright Taylor and Francis Group, LLC |
| Название | One-Step Synthesis of Acetylenes from Ketones |
| Тип | research-article |
| DOI | 10.1080/00397917408062050 |
| Electronic ISSN | 1532-2432 |
| Print ISSN | 0039-7911 |
| Журнал | Synthetic Communications |
| Том | 4 |
| Первая страница | 25 |
| Последняя страница | 27 |
| Аффилиация | Wong, Chiu Ming; Department of Chemistry, University of Manitoba |
| Аффилиация | Ho, Tse-Lok; Department of Chemistry, University of Manitoba |
| Выпуск | 1 |
| Библиографическая ссылка | Jacobs, T. L. 1949. Org. Reactions, 5: 1 T. F. Rutledge, “Acetylenic Compounds” Chap. 3, Reinhold, New York, 1968 |
| Библиографическая ссылка | Isaacs, N. S. and Kirkpatrick, D. 1972. J. C. S. Chem. Commun., : 443 |
