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Автор V., Merlin
Автор P., Kritsalis
Автор L., Coudurier
Автор N., Eustathopoulos
Дата выпуска 1991
dc.description ABSTRACTFor a given non-reactive metal M- refractory oxide system, the influence of a metallic solute A on interfacial chemistry and wetting depends mainly on the value of ε<sub>O−A</sub> the Wagner interaction parameter which quantifies the solute A-solute oxygen interactions in the liquid matrix M.For ε<sub>O−A</sub> < 0 (moderate attraction between solutes A and O) additions of A in M enhance dissolution of oxide in the liquid alloy, thereby increasing the dissolved oxygen content. The O-A clusters formed are adsorbed at the metal-oxide interface leading to an increase in both wettability and adhesion energy. For ε<sub>O−A</sub> ≪0 (strong A-O interactions), solute A can also form an oxide by reduction of the substrate. The more metallic in character this oxide is, the more wettable it will be by molten metal.
Формат application.pdf
Издатель Cambridge University Press
Копирайт Copyright © Materials Research Society 1992
Название Thermodynamic Factors Governing Interfacial Chemistry And Wetting In Binary Alloy-Refractory Oxide Systems.
Тип research-article
DOI 10.1557/PROC-238-511
Electronic ISSN 1946-4274
Print ISSN 0272-9172
Журнал MRS Proceedings
Том 238
Аффилиация V. Merlin; L.T.P.C.M., URA. 29. I.N.P.G.. D.U., ENSEEG, Bp. 75 38402 Saint Martin d'Hères Cedex, France.
Аффилиация P. Kritsalis; L.T.P.C.M., URA. 29. I.N.P.G.. D.U., ENSEEG, Bp. 75 38402 Saint Martin d'Hères Cedex, France.
Аффилиация L. Coudurier; L.T.P.C.M., URA. 29. I.N.P.G.. D.U., ENSEEG, Bp. 75 38402 Saint Martin d'Hères Cedex, France.
Аффилиация N. Eustathopoulos; L.T.P.C.M., URA. 29. I.N.P.G.. D.U., ENSEEG, Bp. 75 38402 Saint Martin d'Hères Cedex, France.

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