Автор |
Tiwari, P. |
Автор |
Zheleva, T. |
Автор |
Morimoto, A. |
Автор |
Shukla, V.N. |
Автор |
Narayan, J. |
dc.description |
ABSTRACTWe have fabricated high-quality <001> textured Pb(Zr<sub>0.54</sub>Ti<sub>0.46</sub>)O<sub>3</sub> (PZT) thin films on (001)Si with interposing <001> textured YBa<sub>2</sub>Cu<sub>3</sub>O<sub>7−δ</sub> (YBCO) and yttria-stabilized zirconia (YSZ) buffer layers using pulsed laser deposition (KrF excimer laser, λ=248 nm, τ=20 nanoseconds). The YBCO layer provides a seed for PZT growth and can also act as an electrode for the PZT films, whereas YSZ provides a diffusion barrier as well as a seed for the growth of YBCO films on (001)Si. These heterostructures were characterized using X-ray diffraction, high-resolution transmission electron microscopy and Rutherford backscattering techniques. The YSZ films were deposited in oxygen ambient (∼9X10<sup>−4</sup> torr) at 775°C on (001)Si substrate having <001>YSZ// <001>Si texture. The YBCO thin films were deposited in-situ in oxygen ambient (200 mtorr) at 650°C. Temperature and oxygen ambient for the PZT deposition were optimized to be 530°C and 0.4–0.6 torr, respectively. The laser fluence to deposit this multistructure was 2.5–5.0 J/cm<sup>2</sup>. The <001> textured perovskite PZT films showed a dielectric constant of 800–1000, a saturation polarization of 37.81 μC/cm<sup>2</sup>, remnant polarization of 24.38 μC/cm<sup>2</sup> and a coersive field of 125 kV/cm. The effects of processing parameters on microstructure and ferroelectric properties of PZT films and device implications of these structures are discussed. |
Формат |
application.pdf |
Издатель |
Cambridge University Press |
Копирайт |
Copyright © Materials Research Society 1993 |
Название |
Preparation of Pb(Zr<sub>0.54</sub>Ti<sub>0.46</sub>)O<sub>3</sub> Thin Films on (100)Si Using Textured YBa<sub>2</sub>Cu<sub>3</sub>O<sub>7−δ</sub> and Yttria-Stabilized Zirconia Buffer Layers by Laser Physical Vapor Deposition Technique |
Тип |
research-article |
DOI |
10.1557/PROC-285-397 |
Electronic ISSN |
1946-4274 |
Print ISSN |
0272-9172 |
Журнал |
MRS Proceedings |
Том |
285 |
Аффилиация |
Tiwari P.; Department of Materials Science and Engineering North Carolina State University |
Аффилиация |
Zheleva T.; Department of Materials Science and Engineering North Carolina State University |
Аффилиация |
Morimoto A.; Department of Materials Science and Engineering North Carolina State University |
Аффилиация |
Shukla V.N.; Department of Materials Science and Engineering North Carolina State University |
Аффилиация |
Narayan J.; Department of Materials Science and Engineering North Carolina State University |